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dc.contributor.authorHenkelis, Susan Elizabeth
dc.contributor.authorMazur, Michal
dc.contributor.authorRice, Cameron Mark
dc.contributor.authorWheatley, Paul Stewart
dc.contributor.authorAshbrook, Sharon E.
dc.contributor.authorMorris, Russell Edward
dc.date.accessioned2019-04-04T10:30:51Z
dc.date.available2019-04-04T10:30:51Z
dc.date.issued2019-03-13
dc.identifier.citationHenkelis , S E , Mazur , M , Rice , C M , Wheatley , P S , Ashbrook , S E & Morris , R E 2019 , ' Kinetics and mechanism of the hydrolysis and rearrangement processes within the assembly-disassembly-organization-reassembly synthesis of zeolites ' , Journal of the American Chemical Society , vol. 141 , no. 10 , pp. 4453-4459 . https://doi.org/10.1021/jacs.9b00643en
dc.identifier.issn0002-7863
dc.identifier.otherPURE: 258120663
dc.identifier.otherPURE UUID: f62ce154-749d-44b8-add7-33c60f94ea41
dc.identifier.otherORCID: /0000-0002-4538-6782/work/56638940
dc.identifier.otherScopus: 85062882818
dc.identifier.otherWOS: 000461537700041
dc.identifier.otherORCID: /0000-0001-7809-0315/work/61622103
dc.identifier.urihttp://hdl.handle.net/10023/17442
dc.descriptionThe authors would like to thank the EPSRC (grants: EP/K025112/1; EP/K005499/1; EP/K503162/1; EP/N509759/1) for funding opportunities. R.E.M., and M.M. would like to acknowledge OP VVV "Excellent Research Teams", project No. CZ.02.1.01/0.0/0.0/15_003/0000417 - CUCAM. We would like to thank the ERC (Advanced Grant 787073 “ADOR”).en
dc.description.abstractThe hydrolysis (disassembly, D) and rearrangement (organization, O) steps of the assembly-disassembly-organization-reassembly (ADOR) process for the synthesis of zeolites have been studied. Germanium–rich UTL was subjected to hydrolysis conditions in water to understand the effects of temperature (100, 92, 85, 81, 77, and 70 °C). Samples were taken periodically over an 8–37 h period and each sample was analyzed by powder X-ray diffraction. The results show that the hydrolysis step is solely dependent on the presence of liquid water, whereas the rearrangement is dependent on the temperature of the system. The kinetics have been investigated using the Avrami-Erofeev model. With increasing temperature, an increase in rate of reaction for the rearrangement step was observed and the Arrhenius equation was used to ascertain an apparent activation energy for the rearrangement from the kinetic product of the disassembly (IPC-1P) to the thermodynamic product of the rearrangement (IPC-2P). From this information a mechanism for this transformation can be postulated.
dc.format.extent7
dc.language.isoeng
dc.relation.ispartofJournal of the American Chemical Societyen
dc.rightsCopyright © 2019 American Chemical Society. This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.en
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subjectBDCen
dc.subjectR2Cen
dc.subject.lccQDen
dc.titleKinetics and mechanism of the hydrolysis and rearrangement processes within the assembly-disassembly-organization-reassembly synthesis of zeolitesen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1021/jacs.9b00643
dc.description.statusPeer revieweden


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