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Reactivity of hemilabile pyridyl- and methyl-substituted pyrimidylselenolates with [MCl2(dppf)] (M = Pd, Pt; dppf = bis(diphenylphisphino)ferrocene)

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dc.contributor.authorChauhan, Rohit Singh
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorYadav, Seema
dc.contributor.authorDash, Chandrakanta
dc.date.accessioned2019-03-30T00:37:59Z
dc.date.available2019-03-30T00:37:59Z
dc.date.issued2018-06-01
dc.identifier.citationChauhan , R S , Cordes , D B , Slawin , A M Z , Yadav , S & Dash , C 2018 , ' Reactivity of hemilabile pyridyl- and methyl-substituted pyrimidylselenolates with [MCl 2 (dppf)] (M = Pd, Pt; dppf = bis(diphenylphisphino)ferrocene) ' , Inorganica Chimica Acta , vol. 478 , pp. 125-129 . https://doi.org/10.1016/j.ica.2018.03.034en
dc.identifier.issn0020-1693
dc.identifier.otherPURE: 252702670
dc.identifier.otherPURE UUID: 9874e7bf-f831-4423-8a5d-b6f83b8acd69
dc.identifier.otherRIS: urn:E5A47BA56D5978E2B7C9F11129ACD0D5
dc.identifier.otherScopus: 85045253409
dc.identifier.otherORCID: /0000-0002-5366-9168/work/43387996
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861439
dc.identifier.otherWOS: 000430989200016
dc.identifier.urihttps://hdl.handle.net/10023/17401
dc.descriptionOne of the authors (RSC) is grateful to DST for the financial support under the DST young scientist scheme YSS/2014/000797.en
dc.description.abstractThe bis(diphenylphisphino)ferrocene (dppf) derived palladium analogue of [PdCl2(dppf)] on reaction with the sodium salt of pyridyl/pyrimidyl selenolate yielded mononuclear cis configured complex [Pd(SeAr)2(dppf)] (Ar = C5H4N, C4H(4,6-Me)2N2), as did the platinum precursor [PtCl2(dppf)] with methyl substituted pyrimidyl salt giving [Pt{SeC4H(4,6-Me)2N2}2(dppf)]. In contrast, the reaction of platinum precursor with the sodium salt of pyridylselenolate gave two different complexes [Pt2(μ-SeC5H4N)2(dppf)2]2+ and [Pt(Cl)(SeC5H4N)(dppf)] depending in the reaction solvent. These complexes were characterized by elemental analysis and NMR (1H, 31P) spectroscopy. The molecular structure of [Pt{SeC4H(4,6-Me)2N2}2(dppf)] was established by single crystal X-ray diffraction analysis.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofInorganica Chimica Actaen
dc.rights© 2018 Elsevier B. V. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1016/j.ica.2018.03.034en
dc.subjectSelenolateen
dc.subjectNMRen
dc.subjectX-rayen
dc.subjectdppfen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleReactivity of hemilabile pyridyl- and methyl-substituted pyrimidylselenolates with [MCl2(dppf)] (M = Pd, Pt; dppf = bis(diphenylphisphino)ferrocene)en
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1016/j.ica.2018.03.034
dc.description.statusPeer revieweden
dc.date.embargoedUntil2019-03-30


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