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Reactivity of hemilabile pyridyl- and methyl-substituted pyrimidylselenolates with [MCl2(dppf)] (M = Pd, Pt; dppf = bis(diphenylphisphino)ferrocene)
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dc.contributor.author | Chauhan, Rohit Singh | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Yadav, Seema | |
dc.contributor.author | Dash, Chandrakanta | |
dc.date.accessioned | 2019-03-30T00:37:59Z | |
dc.date.available | 2019-03-30T00:37:59Z | |
dc.date.issued | 2018-06-01 | |
dc.identifier | 252702670 | |
dc.identifier | 9874e7bf-f831-4423-8a5d-b6f83b8acd69 | |
dc.identifier | 85045253409 | |
dc.identifier | 000430989200016 | |
dc.identifier.citation | Chauhan , R S , Cordes , D B , Slawin , A M Z , Yadav , S & Dash , C 2018 , ' Reactivity of hemilabile pyridyl- and methyl-substituted pyrimidylselenolates with [MCl 2 (dppf)] (M = Pd, Pt; dppf = bis(diphenylphisphino)ferrocene) ' , Inorganica Chimica Acta , vol. 478 , pp. 125-129 . https://doi.org/10.1016/j.ica.2018.03.034 | en |
dc.identifier.issn | 0020-1693 | |
dc.identifier.other | RIS: urn:E5A47BA56D5978E2B7C9F11129ACD0D5 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/43387996 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861439 | |
dc.identifier.uri | https://hdl.handle.net/10023/17401 | |
dc.description | One of the authors (RSC) is grateful to DST for the financial support under the DST young scientist scheme YSS/2014/000797. | en |
dc.description.abstract | The bis(diphenylphisphino)ferrocene (dppf) derived palladium analogue of [PdCl2(dppf)] on reaction with the sodium salt of pyridyl/pyrimidyl selenolate yielded mononuclear cis configured complex [Pd(SeAr)2(dppf)] (Ar = C5H4N, C4H(4,6-Me)2N2), as did the platinum precursor [PtCl2(dppf)] with methyl substituted pyrimidyl salt giving [Pt{SeC4H(4,6-Me)2N2}2(dppf)]. In contrast, the reaction of platinum precursor with the sodium salt of pyridylselenolate gave two different complexes [Pt2(μ-SeC5H4N)2(dppf)2]2+ and [Pt(Cl)(SeC5H4N)(dppf)] depending in the reaction solvent. These complexes were characterized by elemental analysis and NMR (1H, 31P) spectroscopy. The molecular structure of [Pt{SeC4H(4,6-Me)2N2}2(dppf)] was established by single crystal X-ray diffraction analysis. | |
dc.format.extent | 5 | |
dc.format.extent | 731924 | |
dc.language.iso | eng | |
dc.relation.ispartof | Inorganica Chimica Acta | en |
dc.subject | Selenolate | en |
dc.subject | NMR | en |
dc.subject | X-ray | en |
dc.subject | dppf | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Reactivity of hemilabile pyridyl- and methyl-substituted pyrimidylselenolates with [MCl2(dppf)] (M = Pd, Pt; dppf = bis(diphenylphisphino)ferrocene) | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1016/j.ica.2018.03.034 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2019-03-30 |
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