Modulating the expression of chirality in a mechanically chiral rotaxane
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The expression of mechanical chirality by a hydrogen bond templated rotaxane, as detected by 1H NMR spectroscopy, may be modulated by affecting the co-conformational behaviour of the rotaxane through varying solvent or by addition of acid and base.
Gell , C E , McArdle-Ismaguilov , T A & Evans , N H 2019 , ' Modulating the expression of chirality in a mechanically chiral rotaxane ' , Chemical Communications , vol. 55 , no. 11 , pp. 1576-1579 . https://doi.org/10.1039/C8CC10044F
Copyright © 2019 The Author(s). Open Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
DescriptionWe express our appreciation to the Faculty of Science and Technology at Lancaster University for a PhD studentship (C. E. G.) and the EPSRC (Institutional Sponsorship Grant: EP/P511183/1) for financial support of an Equality and Diversity internship (T. A. M.-I). N. H. E. also wishes to thank the Royal Society of Chemistry for a Research Grant that funded some preliminary experiments on chiral rotaxanes.
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