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dc.contributor.authorTurner, James
dc.contributor.authorBuehl, Michael
dc.identifier.citationTurner , J & Buehl , M 2018 , ' The infrared dynamics of iron diene complexes ' , Journal of Physical Chemistry A , vol. 122 , no. 14 , pp. 3497-3505 .
dc.identifier.otherPURE: 252203147
dc.identifier.otherPURE UUID: e34b8dee-8b9b-404c-ad3a-272120b181cd
dc.identifier.otherScopus: 85045392959
dc.identifier.otherWOS: 000430255600001
dc.description.abstractThe temperature-dependence of the low frequency C-O bands in the IR spectrum of [(η4-norbornadiene)Fe(CO)3], reminiscent of signal coalescence in dynamic NMR, was interpreted by Grevels (in 1987) as chemical exchange due to very fast rotation of the diene group. Since then there has been both support and objection to this interpretation. In this Review we discuss these various claims involving both one- and two-dimensional IR and, largely on the basis of new DFT calculations, furnish support for Grevels’s original interpretation.
dc.relation.ispartofJournal of Physical Chemistry Aen
dc.rights© 2018 American Chemical Society. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at
dc.subjectQD Chemistryen
dc.titleThe infrared dynamics of iron diene complexesen
dc.typeJournal itemen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.description.statusPeer revieweden

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