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The infrared dynamics of iron diene complexes

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dc.contributor.authorTurner, James
dc.contributor.authorBuehl, Michael
dc.date.accessioned2019-02-02T00:33:48Z
dc.date.available2019-02-02T00:33:48Z
dc.date.issued2018-04-12
dc.identifier252203147
dc.identifiere34b8dee-8b9b-404c-ad3a-272120b181cd
dc.identifier85045392959
dc.identifier000430255600001
dc.identifier.citationTurner , J & Buehl , M 2018 , ' The infrared dynamics of iron diene complexes ' , Journal of Physical Chemistry A , vol. 122 , no. 14 , pp. 3497-3505 . https://doi.org/10.1021/acs.jpca.7b12309en
dc.identifier.issn1089-5639
dc.identifier.urihttps://hdl.handle.net/10023/16989
dc.description.abstractThe temperature-dependence of the low frequency C-O bands in the IR spectrum of [(η4-norbornadiene)Fe(CO)3], reminiscent of signal coalescence in dynamic NMR, was interpreted by Grevels (in 1987) as chemical exchange due to very fast rotation of the diene group. Since then there has been both support and objection to this interpretation. In this Review we discuss these various claims involving both one- and two-dimensional IR and, largely on the basis of new DFT calculations, furnish support for Grevels’s original interpretation.
dc.format.extent9
dc.format.extent847800
dc.language.isoeng
dc.relation.ispartofJournal of Physical Chemistry Aen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleThe infrared dynamics of iron diene complexesen
dc.typeJournal itemen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1021/acs.jpca.7b12309
dc.description.statusPeer revieweden
dc.date.embargoedUntil2019-02-02


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