On the molecular origin of charge separation at the donor-acceptor interface
MetadataShow full item record
Altmetrics Handle Statistics
Altmetrics DOI Statistics
Fullerene-based acceptors have dominated organic solar cells for almost two decades. It is only within the last few years that alternative acceptors rival their dominance, introducing much more flexibility in the optoelectronic properties of these material blends. However, a fundamental physical understanding of the processes that drive charge separation at organic heterojunctions is still missing but urgently needed to direct further material improvements. Here we use a combined experimental and theoretical approach to understand the intimate mechanisms by which molecular structure contributes to exciton dissociation, charge separation, and charge recombination at the donor-acceptor (D-A) interface. We use model systems comprised of polythiophene-based donor and rylene diimide-based acceptor polymers and perform a detailed density functional theory (DFT) investigation. The results point to the roles that geometric deformations and direct-contact intermolecular polarization play in establishing a driving force (energy gradient) for the optoelectronic processes taking place at the interface. A substantial impact for this driving force is found to stem from polymer deformations at the interface, a finding that can clearly lead to new design approaches in the development of the next generation of conjugated polymers and small molecules.
Sini , G , Schubert , M , Risko , C , Roland , S , Lee , O , Chen , Z , Richter , T , Dolfen , D , Coropceanu , V , Ludwigs , S , Scherf , U , Facchetti , A , Fréchet , J & Neher , D 2018 , ' On the molecular origin of charge separation at the donor-acceptor interface ' , Advanced Energy Materials , vol. 8 , no. 12 , 1702232 . https://doi.org/10.1002/aenm.201702232
Advanced Energy Materials
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1002/aenm.201702232
DescriptionC.R. thanks the University of Kentucky Vice President for Research and the Department of the Navy, Office of Naval Research (Award No. N00014-16-1-2985) for support. V.C. thanks the Department of the Navy, Office of Naval Research (Awards Nos. N00014-14-1-0580 and N00014-16-1-2520) for support. M.S. and D.D. acknowledge funding by the German Science Foundation through the SPP 1355 “Elementary Processes in Organic Photovoltaics.” The research data supporting this paper can be accessed at https://doi.org/10.17630/a6935caf-f7ed-48b2-b131-68ae72a26629.
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.