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dc.contributor.authorHierlinger, Claus
dc.contributor.authorFlint, Heather V.
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorGibson, Elizabeth A.
dc.contributor.authorJacquemin, Denis
dc.contributor.authorGuerchais, Véronique
dc.contributor.authorZysman-Colman, Eli
dc.identifier.citationHierlinger , C , Flint , H V , Cordes , D B , Slawin , A M Z , Gibson , E A , Jacquemin , D , Guerchais , V & Zysman-Colman , E 2018 , ' A panchromatic, near infrared Ir(III) emitter bearing a tripodal C^N^C ligand as a dye for dye-sensitized solar cells ' , Polyhedron , vol. 140 , pp. 109-115 .
dc.identifier.otherPURE: 251685739
dc.identifier.otherPURE UUID: 4ea20f1f-308f-4b00-b43d-6ed909702065
dc.identifier.otherScopus: 85038936823
dc.identifier.otherORCID: /0000-0002-5366-9168/work/39714958
dc.identifier.otherORCID: /0000-0001-7183-6022/work/56639099
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861740
dc.identifier.otherWOS: 000424185400014
dc.descriptionC.H. acknowledges the Région Bretagne, France for funding. EZ-C acknowledges the University of St Andrews and EPSRC (EP/M02105X/1) for financial support. EAG and HVF thank the ERC for a Starting Grant (p-TYPE, 715354).en
dc.description.abstractThe synthesis of a new complex of the form [Ir(C^N^C)(N^N)Cl] [where C^N^C = 2-(bis(4-(tert-butyl)phenyl)methyl)pyridinato (dtBubnpy, L1 ) and N^N is diethyl [2,2'-bipyridine]-4,4'-dicarboxylate (deeb)] is reported. The crystal structure reveals an unusual tripodal tridentate C^N^C ligand forming three six-membered rings around the iridium center. The photophysical and electrochemical properties suggest the use of this complex as a dye in dye-sensitized solar cells. Time-Dependent Density Functional Theory (TD-DFT) calculations have been used to reveal the nature of the excited-states.
dc.rights© 2017 Elsevier Ltd. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at
dc.subjectNIR emissionen
dc.subjectSolar cellen
dc.subjectQD Chemistryen
dc.titleA panchromatic, near infrared Ir(III) emitter bearing a tripodal C^N^C ligand as a dye for dye-sensitized solar cellsen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.description.statusPeer revieweden

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