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A panchromatic, near infrared Ir(III) emitter bearing a tripodal C^N^C ligand as a dye for dye-sensitized solar cells
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dc.contributor.author | Hierlinger, Claus | |
dc.contributor.author | Flint, Heather V. | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Gibson, Elizabeth A. | |
dc.contributor.author | Jacquemin, Denis | |
dc.contributor.author | Guerchais, Véronique | |
dc.contributor.author | Zysman-Colman, Eli | |
dc.date.accessioned | 2018-12-10T09:37:25Z | |
dc.date.available | 2018-12-10T09:37:25Z | |
dc.date.issued | 2018-02-08 | |
dc.identifier | 251685739 | |
dc.identifier | 4ea20f1f-308f-4b00-b43d-6ed909702065 | |
dc.identifier | 85038936823 | |
dc.identifier | 000424185400014 | |
dc.identifier.citation | Hierlinger , C , Flint , H V , Cordes , D B , Slawin , A M Z , Gibson , E A , Jacquemin , D , Guerchais , V & Zysman-Colman , E 2018 , ' A panchromatic, near infrared Ir(III) emitter bearing a tripodal C^N^C ligand as a dye for dye-sensitized solar cells ' , Polyhedron , vol. 140 , pp. 109-115 . https://doi.org/10.1016/j.poly.2017.12.003 | en |
dc.identifier.issn | 0277-5387 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/39714958 | |
dc.identifier.other | ORCID: /0000-0001-7183-6022/work/56639099 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861740 | |
dc.identifier.uri | https://hdl.handle.net/10023/16649 | |
dc.description | C.H. acknowledges the Région Bretagne, France for funding. EZ-C acknowledges the University of St Andrews and EPSRC (EP/M02105X/1) for financial support. EAG and HVF thank the ERC for a Starting Grant (p-TYPE, 715354). | en |
dc.description.abstract | The synthesis of a new complex of the form [Ir(C^N^C)(N^N)Cl] [where C^N^C = 2-(bis(4-(tert-butyl)phenyl)methyl)pyridinato (dtBubnpy, L1 ) and N^N is diethyl [2,2'-bipyridine]-4,4'-dicarboxylate (deeb)] is reported. The crystal structure reveals an unusual tripodal tridentate C^N^C ligand forming three six-membered rings around the iridium center. The photophysical and electrochemical properties suggest the use of this complex as a dye in dye-sensitized solar cells. Time-Dependent Density Functional Theory (TD-DFT) calculations have been used to reveal the nature of the excited-states. | |
dc.format.extent | 8546959 | |
dc.language.iso | eng | |
dc.relation.ispartof | Polyhedron | en |
dc.subject | Iridium | en |
dc.subject | Panchromatic | en |
dc.subject | NIR emission | en |
dc.subject | DSSC | en |
dc.subject | Solar cell | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | A panchromatic, near infrared Ir(III) emitter bearing a tripodal C^N^C ligand as a dye for dye-sensitized solar cells | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1016/j.poly.2017.12.003 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2018-12-09 | |
dc.identifier.grantnumber | EP/M02105X/1 | en |
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