St Andrews Research Repository

St Andrews University Home
View Item 
  •   St Andrews Research Repository
  • University of St Andrews Research
  • University of St Andrews Research
  • University of St Andrews Research
  • View Item
  •   St Andrews Research Repository
  • University of St Andrews Research
  • University of St Andrews Research
  • University of St Andrews Research
  • View Item
  •   St Andrews Research Repository
  • University of St Andrews Research
  • University of St Andrews Research
  • University of St Andrews Research
  • View Item
  • Register / Login
JavaScript is disabled for your browser. Some features of this site may not work without it.

Pressure-induced chemistry for the 2D to 3D transformation of zeolites

Thumbnail
View/Open
Morris_2017_JMCA_Pressure_induced_AAM.pdf (1.078Mb)
SuppInfo_Pressure_induced_JMCA.pdf (591.2Kb)
Date
07/04/2018
Author
Mazur, Michal
Arévalo-López, Angel M.
Wheatley, Paul S.
Bignami, Giulia P. M.
Ashbrook, Sharon E.
Morales-García, Ángel
Nachtigall, Petr
Attfield, J. Paul
Čejka, Jiři
Morris, Russell E.
Funder
EPSRC
EPSRC
Grant ID
EP/K025112/1
EP/L014475/1
Keywords
QD Chemistry
NDAS
Metadata
Show full item record
Abstract
ADOR, an unconventional synthesis strategy based on a four-step mechanism: assembly, disassembly, organization, and reassembly, has opened new possibilities in zeolite chemistry. The ADOR approach led to the discovery of the IPC family of materials with tuneable porosity. Here we present the first pressure-induced ADOR transformation of 2D zeolite precursor IPC-1P into fully crystalline 3D zeolite IPC-2 (OKO topology) using a Walker-type multianvil apparatus under a pressure of 1 GPa at 200 °C. Surprisingly, the high-pressure material is of lower density (higher porosity) than the product obtained from simply calcining the IPC-1P precursor at high temperature, which produces IPC-4 (PCR topology). The sample was characterized by PXRD, 29Si MAS NMR, SEM, and HRTEM. Theoretical calculations suggest that high pressure can lead to the preparation of other ADOR zeolites that have not yet been prepared.
Citation
Mazur , M , Arévalo-López , A M , Wheatley , P S , Bignami , G P M , Ashbrook , S E , Morales-García , Á , Nachtigall , P , Attfield , J P , Čejka , J & Morris , R E 2018 , ' Pressure-induced chemistry for the 2D to 3D transformation of zeolites ' , Journal of Materials Chemistry , vol. 6 , no. 13 , pp. 5255-5259 . https://doi.org/10.1039/C7TA09248B
Publication
Journal of Materials Chemistry
Status
Peer reviewed
DOI
https://doi.org/10.1039/C7TA09248B
ISSN
0959-9428
Type
Journal article
Rights
© 2017 the Authors. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/ 10.1039/C7TA09248B
Description
M.M., P.S.W., G.P.M.B., S.E.A., and R.E.M. thank the EPSRC (grants: EP/K025112/1, EP/L014475/1, and EP/ M506631/1) for funding. M.M., P.N., J.Č. and R.E.M. would like to acknowledge OP VVV "Excellent Research Teams", project No. CZ.02.1.01/0.0/0.0/15_003/0000417 - CUCAM. J.Č. and P.N. acknowledge the Czech Science Foundation (P106/12/G015) for the financial support of this research. J.P.A. acknowledges EPSRC support for the high pressure work.
Collections
  • University of St Andrews Research
URI
http://hdl.handle.net/10023/16482

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.

Advanced Search

Browse

All of RepositoryCommunities & CollectionsBy Issue DateNamesTitlesSubjectsClassificationTypeFunderThis CollectionBy Issue DateNamesTitlesSubjectsClassificationTypeFunder

My Account

Login

Open Access

To find out how you can benefit from open access to research, see our library web pages and Open Access blog. For open access help contact: openaccess@st-andrews.ac.uk.

Accessibility

Read our Accessibility statement.

How to submit research papers

The full text of research papers can be submitted to the repository via Pure, the University's research information system. For help see our guide: How to deposit in Pure.

Electronic thesis deposit

Help with deposit.

Repository help

For repository help contact: Digital-Repository@st-andrews.ac.uk.

Give Feedback

Cookie policy

This site may use cookies. Please see Terms and Conditions.

Usage statistics

COUNTER-compliant statistics on downloads from the repository are available from the IRUS-UK Service. Contact us for information.

© University of St Andrews Library

University of St Andrews is a charity registered in Scotland, No SC013532.

  • Facebook
  • Twitter