Files in this item
Investigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic ligand
Item metadata
dc.contributor.author | Trose, Michael | |
dc.contributor.author | Nahra, Fady | |
dc.contributor.author | Poater, Albert | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Cavallo, Luigi | |
dc.contributor.author | Cazin, Catherine S. J. | |
dc.date.accessioned | 2018-11-01T00:50:02Z | |
dc.date.available | 2018-11-01T00:50:02Z | |
dc.date.issued | 2017-12 | |
dc.identifier | 251832644 | |
dc.identifier | cb6075fe-ff82-49bc-b038-7916f13ee531 | |
dc.identifier | 000417230500018 | |
dc.identifier | 85036619836 | |
dc.identifier | 000417230500018 | |
dc.identifier.citation | Trose , M , Nahra , F , Poater , A , Cordes , D B , Slawin , A M Z , Cavallo , L & Cazin , C S J 2017 , ' Investigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic ligand ' , ACS Catalysis , vol. 7 , no. 12 , pp. 8176-8183 . https://doi.org/10.1021/acscatal.7b02737 | en |
dc.identifier.issn | 2155-5435 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/40075006 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861524 | |
dc.identifier.uri | https://hdl.handle.net/10023/16367 | |
dc.description | The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), the Spanish MINECO (CTQ2014-59832-JIN), and EU (FEDER fund UNGI08-4E-003) for funding. | en |
dc.description.abstract | A family of copper(I)-NHC azolyl complexes was synthesized and deployed in the hydrosilylation of dicyclo-hexylketone to probe the role of the anionic ligand on catalytic performance. The azolyl ligand is shown to have a crucial role in catalytic activity without the need for additives, and this at very low catalyst loading. | |
dc.format.extent | 8 | |
dc.format.extent | 1190804 | |
dc.language.iso | eng | |
dc.relation.ispartof | ACS Catalysis | en |
dc.subject | N-heterocyclic carbenes | en |
dc.subject | Copper(I) | en |
dc.subject | Hydrosilylation | en |
dc.subject | Anionic ligand | en |
dc.subject | Dimer | en |
dc.subject | Autocatalytic | en |
dc.subject | N-Heterocyclic carbene | en |
dc.subject | Efficient enantioselective hydrosilylation | en |
dc.subject | Aryl ketones | en |
dc.subject | Asymmetric hydrosilylation | en |
dc.subject | Catalyzed hydrosilylation | en |
dc.subject | Carbonyl-compounds | en |
dc.subject | CU-I | en |
dc.subject | Copper | en |
dc.subject | Hydride | en |
dc.subject | Reduction | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Investigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic ligand | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1021/acscatal.7b02737 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2018-11-01 |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.