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dc.contributor.authorTrose, Michael
dc.contributor.authorNahra, Fady
dc.contributor.authorPoater, Albert
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorCavallo, Luigi
dc.contributor.authorCazin, Catherine S. J.
dc.date.accessioned2018-11-01T00:50:02Z
dc.date.available2018-11-01T00:50:02Z
dc.date.issued2017-12
dc.identifier.citationTrose , M , Nahra , F , Poater , A , Cordes , D B , Slawin , A M Z , Cavallo , L & Cazin , C S J 2017 , ' Investigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic ligand ' ACS Catalysis , vol. 7 , no. 12 , pp. 8176-8183 . DOI: 10.1021/acscatal.7b02737en
dc.identifier.issn2155-5435
dc.identifier.otherPURE: 251832644
dc.identifier.otherPURE UUID: cb6075fe-ff82-49bc-b038-7916f13ee531
dc.identifier.otherWOS: 000417230500018
dc.identifier.otherScopus: 85036619836
dc.identifier.urihttp://hdl.handle.net/10023/16367
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), the Spanish MINECO (CTQ2014-59832-JIN), and EU (FEDER fund UNGI08-4E-003) for funding.en
dc.description.abstractA family of copper(I)-NHC azolyl complexes was synthesized and deployed in the hydrosilylation of dicyclo-hexylketone to probe the role of the anionic ligand on catalytic performance. The azolyl ligand is shown to have a crucial role in catalytic activity without the need for additives, and this at very low catalyst loading.en
dc.format.extent8en
dc.language.isoeng
dc.relation.ispartofACS Catalysisen
dc.rightsCopyright © 2017 American Chemical Society. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1021/acscatal.7b02737en
dc.subjectN-heterocyclic carbenesen
dc.subjectCopper(I)en
dc.subjectHydrosilylationen
dc.subjectAnionic liganden
dc.subjectDimeren
dc.subjectAutocatalyticen
dc.subjectN-Heterocyclic carbeneen
dc.subjectEfficient enantioselective hydrosilylationen
dc.subjectAryl ketonesen
dc.subjectAsymmetric hydrosilylationen
dc.subjectCatalyzed hydrosilylationen
dc.subjectCarbonyl-compoundsen
dc.subjectCU-Ien
dc.subjectCopperen
dc.subjectHydrideen
dc.subjectReductionen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleInvestigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic liganden
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1021/acscatal.7b02737
dc.description.statusPeer revieweden
dc.date.embargoedUntil01-11-20


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