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dc.contributor.authorTrose, Michael
dc.contributor.authorNahra, Fady
dc.contributor.authorPoater, Albert
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorCavallo, Luigi
dc.contributor.authorCazin, Catherine S. J.
dc.date.accessioned2018-11-01T00:50:02Z
dc.date.available2018-11-01T00:50:02Z
dc.date.issued2017-12
dc.identifier251832644
dc.identifiercb6075fe-ff82-49bc-b038-7916f13ee531
dc.identifier000417230500018
dc.identifier85036619836
dc.identifier000417230500018
dc.identifier.citationTrose , M , Nahra , F , Poater , A , Cordes , D B , Slawin , A M Z , Cavallo , L & Cazin , C S J 2017 , ' Investigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic ligand ' , ACS Catalysis , vol. 7 , no. 12 , pp. 8176-8183 . https://doi.org/10.1021/acscatal.7b02737en
dc.identifier.issn2155-5435
dc.identifier.otherORCID: /0000-0002-5366-9168/work/40075006
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861524
dc.identifier.urihttps://hdl.handle.net/10023/16367
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), the Spanish MINECO (CTQ2014-59832-JIN), and EU (FEDER fund UNGI08-4E-003) for funding.en
dc.description.abstractA family of copper(I)-NHC azolyl complexes was synthesized and deployed in the hydrosilylation of dicyclo-hexylketone to probe the role of the anionic ligand on catalytic performance. The azolyl ligand is shown to have a crucial role in catalytic activity without the need for additives, and this at very low catalyst loading.
dc.format.extent8
dc.format.extent1190804
dc.language.isoeng
dc.relation.ispartofACS Catalysisen
dc.subjectN-heterocyclic carbenesen
dc.subjectCopper(I)en
dc.subjectHydrosilylationen
dc.subjectAnionic liganden
dc.subjectDimeren
dc.subjectAutocatalyticen
dc.subjectN-Heterocyclic carbeneen
dc.subjectEfficient enantioselective hydrosilylationen
dc.subjectAryl ketonesen
dc.subjectAsymmetric hydrosilylationen
dc.subjectCatalyzed hydrosilylationen
dc.subjectCarbonyl-compoundsen
dc.subjectCU-Ien
dc.subjectCopperen
dc.subjectHydrideen
dc.subjectReductionen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleInvestigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic liganden
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1021/acscatal.7b02737
dc.description.statusPeer revieweden
dc.date.embargoedUntil2018-11-01


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