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dc.contributor.authorHolmes, William
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorHarrison, William T. A.
dc.identifier.citationHolmes , W , Cordes , D B , Slawin , A M Z & Harrison , W T A 2018 , ' Template or ligand? Different structural behaviours of aromatic amines in combination with zincophosphite networks ' , Acta Crystallographica Section E: Crystallographic Communications , vol. 74 , no. 10 , pp. 1411-1416 .
dc.identifier.otherPURE: 256246984
dc.identifier.otherPURE UUID: 1232db57-fbff-45b0-9985-5353ea616ee2
dc.identifier.otherScopus: 85054565818
dc.identifier.otherORCID: /0000-0002-5366-9168/work/49580169
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861628
dc.identifier.otherWOS: 000445964500006
dc.description.abstractThe solution-mediated syntheses and crystal structures of catena-poly[bis(2- amino-3-hydroxypyridinium) [zinc-di-μ-phosphonato] dihydrate], {(C5H7N2O)- [Zn(HPO3)2]·2H2O}n, (I), and poly[(benzene-1,2-diamine)(μ 5-phosphonato)- zinc], [Zn(HPO3)(C6H8N2)]n, (II) are described. The extended structure of (I) features [010] anionic chains of vertex-sharing ZnO4 tetrahedra and HPO3 pseudopyramids; these chains are characterized by disorder over major [occupancy 0.7962 (13)] and minor [0.2038 (13)] components, which can be superimposed on each other by a nominal translational shift. The 2-amino-3- hydroxypyridinium cations and water molecules of crystallization interact with the ZnPO chains by way of numerous O-H⋯O and N-H⋯O hydrogen bonds. The structure of (II) features a direct Zn-N bond to the neutral 1,2-diaminobenzene species as part of ZnO3N tetrahedra as well as HPO3 pseudopyramids. The Zn- and P-centred groupings are linked through their Oatom vertices into infinite (010) sheets and the structure is consolidated by N- H⋯O hydrogen bonds and N-H⋯ interactions. The crystal of (I) chosen for data collection was found to be an inversion twin in a 0.56 (2):0.44 (2) domain ratio.
dc.relation.ispartofActa Crystallographica Section E: Crystallographic Communicationsen
dc.rightsCopyright © 2018 The Author(s). This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.en
dc.subjectCrystal structureen
dc.subjectZinc phosphiteen
dc.subjectQD Chemistryen
dc.subjectMaterials Science(all)en
dc.subjectCondensed Matter Physicsen
dc.titleTemplate or ligand? Different structural behaviours of aromatic amines in combination with zincophosphite networksen
dc.typeJournal itemen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.description.statusPeer revieweden

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