Expedient syntheses of neutral and cationic Au(I)–NHC complexes

Veenboer, Richard M. P.; Gasperini, Danila; Nahra, Fady; Cordes, David B.; Slawin, Alexandra M. Z.; Cazin, Catherine S. J.; Nolan, Steven P.

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dc.contributor.author	Veenboer, Richard M. P.
dc.contributor.author	Gasperini, Danila
dc.contributor.author	Nahra, Fady
dc.contributor.author	Cordes, David B.
dc.contributor.author	Slawin, Alexandra M. Z.
dc.contributor.author	Cazin, Catherine S. J.
dc.contributor.author	Nolan, Steven P.
dc.date.accessioned	2018-09-07T23:35:38Z
dc.date.available	2018-09-07T23:35:38Z
dc.date.issued	2017-09-25
dc.identifier	251138696
dc.identifier	0c3e9e6b-a308-4bfa-95ea-34d86d65910e
dc.identifier	85029929274
dc.identifier	000411914000025
dc.identifier.citation	Veenboer , R M P , Gasperini , D , Nahra , F , Cordes , D B , Slawin , A M Z , Cazin , C S J & Nolan , S P 2017 , ' Expedient syntheses of neutral and cationic Au(I)–NHC complexes ' , Organometallics , vol. 36 , no. 18 , pp. 3645–3653 . https://doi.org/10.1021/acs.organomet.7b00622	en
dc.identifier.issn	0276-7333
dc.identifier.other	RIS: urn:82C28BCEC9E2489244051F89B25455AE
dc.identifier.other	ORCID: /0000-0002-5366-9168/work/37071290
dc.identifier.other	ORCID: /0000-0002-9527-6418/work/56861912
dc.identifier.uri	https://hdl.handle.net/10023/15993
dc.description	The European Research Council (ERC) and the Engineering and Physical Sciences Research Council (EPSRC), UK are gratefully acknowledged for their support. Umicore AG is thanked for generous donations of auric acid. S.P.N. thanks the King Abdullah University of Science and Technology (KAUST) for support.	en
dc.description.abstract	The synthesis and isolation of gold(I) precatalysts often requires the generation of several isolable intermediates as well as numerous purification steps. New protocols for the expedient synthesis of neutral [Au(OH)(NHC)] and [Au(CH2COCH3)(NHC)] species from [AuCl(NHC)] or [AuCl(DMS)] precursors bearing a variety of N-heterocyclic carbene (NHC) ligands are presented. These methods can be employed in a telescoping manner for the synthesis of catalytically relevant [Au(NTf2)(NHC)] and [Au(NHC)(NCCH3)][BF4] complexes. These attractive methods are straightforward and practical leading to various complexes in high isolated yields and purity.
dc.format.extent	1059030
dc.language.iso	eng
dc.relation.ispartof	Organometallics	en
dc.subject	QD Chemistry	en
dc.subject	DAS	en
dc.subject.lcc	QD	en
dc.title	Expedient syntheses of neutral and cationic Au(I)–NHC complexes	en
dc.type	Journal article	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.contributor.institution	University of St Andrews. EaSTCHEM	en
dc.identifier.doi	10.1021/acs.organomet.7b00622
dc.description.status	Peer reviewed	en
dc.date.embargoedUntil	2018-09-08
dc.identifier.url	http://pubs.acs.org/doi/suppl/10.1021/acs.organomet.7b00622	en

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