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dc.contributor.authorAitken, R. Alan
dc.contributor.authorMurray, Lorna
dc.contributor.authorSlawin, Alexandra M. Z.
dc.date.accessioned2018-08-29T11:30:07Z
dc.date.available2018-08-29T11:30:07Z
dc.date.issued2018-08-27
dc.identifier.citationAitken , R A , Murray , L & Slawin , A M Z 2018 , ' Further studies on the pyrolytic domino cyclization of stabilized phosphonium ylides bearing an ortho-aminophenyl group ' , Molecules , vol. 23 , no. 9 , 2153 . https://doi.org/10.3390/molecules23092153en
dc.identifier.issn1420-3049
dc.identifier.otherPURE: 255453626
dc.identifier.otherPURE UUID: dbef220a-788a-492c-a148-d6b022b2616f
dc.identifier.otherScopus: 85052642037
dc.identifier.otherORCID: /0000-0001-6959-5311/work/47928985
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861947
dc.identifier.otherWOS: 000447365100066
dc.identifier.urihttp://hdl.handle.net/10023/15902
dc.descriptionThe authors thank the EPSRC (UK) for a DTA studentship (Grant No. EP/P501768/1).en
dc.description.abstractFour new stabilized phosphonium ylides containing a 2-(benzyl(methyl)amino)phenyl group have been prepared and characterized and are found, upon pyrolysis under gas-phase flow conditions, to lose Ph3PO and benzyl radical to afford new heterocyclic products resulting from domino cyclization of both C- and N-centred radicals. Most products arise from processes of the former type and have quinoline, phenanthridine or ring-fused phenanthridine structures, while in one case a process of the latter type leads to a benzocarbazole product. The X-ray structure of a 2-(methyl(tosyl)amino)phenyl ylide is also reported.
dc.format.extent12
dc.language.isoeng
dc.relation.ispartofMoleculesen
dc.rights© 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).en
dc.subjectPhosphonium ylidesen
dc.subjectPyrolysisen
dc.subjectQuinolineen
dc.subjectPhenanthridineen
dc.subjectBenzocarbazoleen
dc.subjectX-ray structureen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleFurther studies on the pyrolytic domino cyclization of stabilized phosphonium ylides bearing an ortho-aminophenyl groupen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.identifier.doihttps://doi.org/10.3390/molecules23092153
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.mdpi.com/1420-3049/23/9/2153#supplementaryen


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