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Diverse derivatives of selenoureas : a synthetic and single crystal structural study
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dc.contributor.author | Hua, Guoxiong | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Du, Junyi | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2018-08-27T08:30:10Z | |
dc.date.available | 2018-08-27T08:30:10Z | |
dc.date.issued | 2018-08-25 | |
dc.identifier | 255553676 | |
dc.identifier | aeeb2685-9683-4a97-9d33-0900f0f91162 | |
dc.identifier | 85052652394 | |
dc.identifier | 000447365100056 | |
dc.identifier.citation | Hua , G , Cordes , D B , Du , J , Slawin , A M Z & Woollins , J D 2018 , ' Diverse derivatives of selenoureas : a synthetic and single crystal structural study ' , Molecules , vol. 23 , no. 9 , 2143 . https://doi.org/10.3390/molecules23092143 | en |
dc.identifier.issn | 1420-3049 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/47725813 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861946 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/59464695 | |
dc.identifier.uri | https://hdl.handle.net/10023/15878 | |
dc.description | The authors are grateful to the University of St Andrews for financial support. | en |
dc.description.abstract | Reacting aroyl chlorides with an equivalent of potassium selenocyanate, followed by treating with an equivalent of 1,2,4-tri-tert-butylaniline at room temperature, resulted in the expected selenoureas and unusual diselenazoles. The selenation of selenourea by Woollins Reagent gave a new selenoformamide. Nucleophilic addition of selenoureas with acyl bromides led to the formation of new carbamimidoselenoates rather than the expected 1,3-selenazoles. The novel compounds prepared were characterised spectroscopically and crystallographically. | |
dc.format.extent | 1886933 | |
dc.language.iso | eng | |
dc.relation.ispartof | Molecules | en |
dc.subject | Selenoureas | en |
dc.subject | Diselenazoles | en |
dc.subject | Selenoformamide | en |
dc.subject | 1,3-Selenazoles | en |
dc.subject | Woollin’s Reagent | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Diverse derivatives of selenoureas : a synthetic and single crystal structural study | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | https://doi.org/10.3390/molecules23092143 | |
dc.description.status | Peer reviewed | en |
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