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dc.contributor.authorHua, Guoxiong
dc.contributor.authorCordes, David B.
dc.contributor.authorDu, Junyi
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2018-08-27T08:30:10Z
dc.date.available2018-08-27T08:30:10Z
dc.date.issued2018-08-25
dc.identifier.citationHua , G , Cordes , D B , Du , J , Slawin , A M Z & Woollins , J D 2018 , ' Diverse derivatives of selenoureas : a synthetic and single crystal structural study ' , Molecules , vol. 23 , no. 9 , 2143 . https://doi.org/10.3390/molecules23092143en
dc.identifier.issn1420-3049
dc.identifier.otherPURE: 255553676
dc.identifier.otherPURE UUID: aeeb2685-9683-4a97-9d33-0900f0f91162
dc.identifier.otherScopus: 85052652394
dc.identifier.otherORCID: /0000-0002-5366-9168/work/47725813
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861946
dc.identifier.otherORCID: /0000-0002-1498-9652/work/59464695
dc.identifier.otherWOS: 000447365100056
dc.identifier.urihttp://hdl.handle.net/10023/15878
dc.descriptionThe authors are grateful to the University of St Andrews for financial support.en
dc.description.abstractReacting aroyl chlorides with an equivalent of potassium selenocyanate, followed by treating with an equivalent of 1,2,4-tri-tert-butylaniline at room temperature, resulted in the expected selenoureas and unusual diselenazoles. The selenation of selenourea by Woollins Reagent gave a new selenoformamide. Nucleophilic addition of selenoureas with acyl bromides led to the formation of new carbamimidoselenoates rather than the expected 1,3-selenazoles. The novel compounds prepared were characterised spectroscopically and crystallographically.
dc.language.isoeng
dc.relation.ispartofMoleculesen
dc.rights© 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).en
dc.subjectSelenoureasen
dc.subjectDiselenazolesen
dc.subjectSelenoformamideen
dc.subject1,3-Selenazolesen
dc.subjectWoollin’s Reagenten
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleDiverse derivatives of selenoureas : a synthetic and single crystal structural studyen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews.Office of the Principalen
dc.identifier.doihttps://doi.org/10.3390/molecules23092143
dc.description.statusPeer revieweden


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