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dc.contributor.authorStueeken, Eva E.
dc.contributor.authorZaloumis, Jon
dc.contributor.authorMeixnerová, Jana
dc.contributor.authorBuick, Roger
dc.identifier.citationStueeken , E E , Zaloumis , J , Meixnerová , J & Buick , R 2017 , ' Differential metamorphic effects on nitrogen isotopes in kerogen extracts and bulk rocks ' , Geochimica et Cosmochimica Acta , vol. 217 , pp. 80-94 .
dc.identifier.otherPURE: 250868793
dc.identifier.otherPURE UUID: e196a289-f895-4a05-b2a0-13b24b10f96a
dc.identifier.otherRIS: urn:0756D247F6C4119AF6AD28079DAC9FD8
dc.identifier.otherScopus: 85028507065
dc.identifier.otherWOS: 000411362000005
dc.identifier.otherORCID: /0000-0001-6861-2490/work/65014406
dc.descriptionThis work was financially supported by a NASA Exobiology grant to RB (# NNX16AI37G), an NSF graduate student research fellowship to JZ, and a NASA postdoctoral fellowship to EES.en
dc.description.abstractThe last decade has seen a steady rise in the number of publications on nitrogen isotopes in sedimentary rocks, which have become an established tool for investigating the evolution of life and environmental conditions. Nitrogen is contained in sedimentary rocks in two different phases: bound to kerogen or substituted in potassic minerals (mostly K-bearing phyllosilicates and feldspars). Isotopic measurements and interpretations typically focus either on kerogen extracts alone or on bulk rocks that include both phases. The community is split about which sample type more accurately captures the original composition of the biomass. To address this question, we combined nitrogen isotopes and carbon-to-nitrogen ratios with carbon-to-hydrogen ratios which act as an independent proxy for metamorphic alteration. Our results reveal that metamorphism drives kerogen-bound nitrogen isotopically lighter while silicate-bound nitrogen becomes heavier. For rocks up to greenschist facies, the isotopic effect of this internal partitioning (up to 3-4‰) is larger than the isotopic effect of metamorphic nitrogen loss from the system (up to 1-2‰). The opposite may be true for higher metamorphic grades. We conclude that for low-grade sedimentary rocks with more than 60% of their total nitrogen residing in the silicate phase the primary isotopic composition of the biomass is best approximated by the bulk rock measurement, whereas for high-grade rocks the kerogen extract may be the more accurate proxy. The isotopic difference between nitrogen phases can thus serve as a rough indicator of the degree of metamorphic alteration.
dc.relation.ispartofGeochimica et Cosmochimica Actaen
dc.rights© 2017 Elsevier Ltd. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at
dc.subjectNitrogen isotopesen
dc.subjectGE Environmental Sciencesen
dc.subjectQH301 Biologyen
dc.titleDifferential metamorphic effects on nitrogen isotopes in kerogen extracts and bulk rocksen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews.School of Earth & Environmental Sciencesen
dc.contributor.institutionUniversity of St Andrews.St Andrews Centre for Exoplanet Scienceen
dc.description.statusPeer revieweden

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