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The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C-H···O hydrogen bonds and nitro···π(arene) interactions

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Girisha_2018_ACECC_3_Dsupramolecularassembly_CC.pdf (701.7Kb)
Date
08/2018
Author
Girisha, Marisiddaiah
Sagar, Belakavadi K.
Yathirajan, Hemmige S.
Rathore, Ravindranath S.
Glidewell, Christopher
Keywords
Schiff bases
Crystal structure
Disorder
Molecular conformation
Hydrogen bonding
nitro···π(arene) interactions
Supramolecular assembly
QD Chemistry
DAS
Metadata
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Abstract
In the molecule of the title compound, C15H14N2O2, the 2-ethylphenyl group is disordered over two sets of atomic sites having occupancies of 0.515 (19) and 0.485 (19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)°. A combination of C-H···O hydrogen bonds and nitro...π(arene) interactions links the molecules into a continuous three-dimensional framework structure. Comparisons are made with the structures of some related compounds.
Citation
Girisha , M , Sagar , B K , Yathirajan , H S , Rathore , R S & Glidewell , C 2018 , ' The crystal structure of ( E )-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C-H···O hydrogen bonds and nitro···π(arene) interactions ' , Acta Crystallographica Section E , vol. 74 , no. 8 , pp. 1071-1074 . https://doi.org/10.1107/S2056989018009544
Publication
Acta Crystallographica Section E
Status
Peer reviewed
DOI
https://doi.org/10.1107/S2056989018009544
ISSN
2056-9890
Type
Journal article
Rights
© 2018 The Author(s). This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Description
HSYacknowledges the UGC (India) for the award of a UGC– BSR Faculty Fellowship and MG thanks the UGC for the award of a Rajeev Gandhi Fellowship.
Collections
  • University of St Andrews Research
URI
http://hdl.handle.net/10023/15793

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