St Andrews Research Repository

St Andrews University Home
View Item 
  •   St Andrews Research Repository
  • Chemistry (School of)
  • Chemistry
  • Chemistry Theses
  • View Item
  •   St Andrews Research Repository
  • Chemistry (School of)
  • Chemistry
  • Chemistry Theses
  • View Item
  •   St Andrews Research Repository
  • Chemistry (School of)
  • Chemistry
  • Chemistry Theses
  • View Item
  • Login
JavaScript is disabled for your browser. Some features of this site may not work without it.

Vapour pressures of some inorganic sulphates at high temperatures

Thumbnail
View/Open
GomatamJagannathanPhDThesis.pdf (24.08Mb)
Date
1977
Author
Jagannathan, Gomatam V.
Supervisor
Wyatt, P. A. H. (Peter Arthur Harris)
Metadata
Show full item record
Abstract
The vapour pressures of some inorganic sulphates at high temperatures were determined by the combined use of the Knudsen effusion, transpiration, and matrix isolation methods. After a detailed comparison with the results of other investigators, it is concluded that the principal vapour species in the case of K₂SO₄, Rb₂SO₄, and Cs₂SO₄ are the undecomposed sulphate molecules themselves, and in the case of Li₂SO₄ the decomposition products, Li, SO₂, and O₂. The sodium salt also decomposes to some extent into Na, SO₂, and O₂, but it is deduced that the vapour concentration of the species Na₂O₄ is probably greater than was formerly supposed. The decomposition of alkaline earth sulphates is also discussed, especially in the light of the dependence of the Knudsen effusion results upon the size of the orifice used. On the basis of the vapour constitutions deduced, thermodynamic functions for the important species present are tabulated up to 1400 K or above. Reference is also made to the function of sodium sulphate in the glass-making industry and to the possible mechanism of its corrosive action on furnace walls.
Type
Thesis, PhD Doctor of Philosophy
Collections
  • Chemistry Theses
URI
http://hdl.handle.net/10023/15500

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.

Advanced Search

Browse

All of RepositoryCommunities & CollectionsBy Issue DateNamesTitlesSubjectsClassificationTypeFunderThis CollectionBy Issue DateNamesTitlesSubjectsClassificationTypeFunder

My Account

Login

Open Access

To find out how you can benefit from open access to research, see our library web pages and Open Access blog. For open access help contact: openaccess@st-andrews.ac.uk.

Accessibility

Read our Accessibility statement.

How to submit research papers

The full text of research papers can be submitted to the repository via Pure, the University's research information system. For help see our guide: How to deposit in Pure.

Electronic thesis deposit

Help with deposit.

Repository help

For repository help contact: Digital-Repository@st-andrews.ac.uk.

Give Feedback

Cookie policy

This site may use cookies. Please see Terms and Conditions.

Usage statistics

COUNTER-compliant statistics on downloads from the repository are available from the IRUS-UK Service. Contact us for information.

© University of St Andrews Library

University of St Andrews is a charity registered in Scotland, No SC013532.

  • Facebook
  • Twitter