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Perspective : current advances in solid-state NMR spectroscopy

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Ashbrook_2018_JoCP_Perspective_SSNMR_AAM.pdf (1.681Mb)
Date
28/07/2018
Author
Ashbrook, Sharon E.
Hodgkinson, Paul
Keywords
QD Chemistry
T-NDAS
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Abstract
In contrast to the rapid and revolutionary impact of solution-state NMR on modern chemistry, the field of solid-state NMR has matured more slowly. This reflects the major technical challenges of much reduced spectral resolution and sensitivity in solid-state as compared to solution-state spectra, as well as the relative complexity of the solid state. In this Perspective, we outline the technique developments that have pushed resolution to intrinsic limits and the approaches, including ongoing major developments in the field of Dynamic Nuclear Polarisation, that have enhanced spectral sensitivity. The information on local structure and dynamics that can be obtained using these gains in sensitivity and resolution is illustrated with a diverse range of examples from large biomolecules, to energy materials and pharmaceuticals, and from both ordered and highly disordered materials. We discuss how parallel developments in quantum chemical calculation, particularly density functional theory, have enabled experimental data to be translated into directly into information on local structure and dynamics, giving rise to the developing field of “NMR crystallography”.
Citation
Ashbrook , S E & Hodgkinson , P 2018 , ' Perspective : current advances in solid-state NMR spectroscopy ' , Journal of Chemical Physics , vol. 149 , no. 4 , 040901 . https://doi.org/10.1063/1.5038547
Publication
Journal of Chemical Physics
Status
Peer reviewed
DOI
https://doi.org/10.1063/1.5038547
ISSN
0021-9606
Type
Journal item
Rights
© 2018 the Authors, published by AIP. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1063/1.5038547
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  • University of St Andrews Research
URL
https://aip.scitation.org/journal/jcp
URI
http://hdl.handle.net/10023/14653

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