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Organocatalytic chemoselective primary alcohol oxidation and subsequent cleavage of lignin model compounds and lignin
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dc.contributor.author | Dabral, Saumya | |
dc.contributor.author | Hernández, José G. | |
dc.contributor.author | Kamer, Paul C. J. | |
dc.contributor.author | Bolm, Carsten | |
dc.date.accessioned | 2018-06-14T23:32:10Z | |
dc.date.available | 2018-06-14T23:32:10Z | |
dc.date.issued | 2017-07-10 | |
dc.identifier | 250288835 | |
dc.identifier | 4e785716-1117-4f22-af3f-fc5b2ef28735 | |
dc.identifier | 85020703070 | |
dc.identifier | 000405080200002 | |
dc.identifier.citation | Dabral , S , Hernández , J G , Kamer , P C J & Bolm , C 2017 , ' Organocatalytic chemoselective primary alcohol oxidation and subsequent cleavage of lignin model compounds and lignin ' , CHEMSUSCHEM , vol. 10 , no. 13 , pp. 2707–2713 . https://doi.org/10.1002/cssc.201700703 | en |
dc.identifier.issn | 1864-564X | |
dc.identifier.other | Bibtex: urn:7afee53958adc832ad445d88b165bbd9 | |
dc.identifier.uri | https://hdl.handle.net/10023/14093 | |
dc.description | This research was supported by the European Union (Marie Curie ITN “SuBiCat” PITN-GA-2013-607044, S.D.) and by the Distinguished Professorship Program at RWTH Aachen University funded by the Excellence Initiative of the German federal and state governments. | en |
dc.description.abstract | A one-pot two-step degradation of lignin β-O-4 model compounds initiated by preferred oxidation of the primary over the secondary hydroxyl groups with a TEMPO/DAIB system has been developed [TEMPO=2,2,6,6-tetramethylpiperidine-N-oxyl, DAIB=(diacetoxy)iodobenzene]. The oxidised products are then cleaved by proline-catalysed retro-aldol reactions. This degradation methodology produces simple aromatics in good yields from lignin model compounds at room temperature with an extension to organosolv beech-wood lignin ( L1 ) resulting in known cleavage products. | |
dc.format.extent | 2109245 | |
dc.format.extent | 4260531 | |
dc.language.iso | eng | |
dc.relation.ispartof | CHEMSUSCHEM | en |
dc.subject | Alcohol oxidation | en |
dc.subject | Bond cleavage | en |
dc.subject | Lignin | en |
dc.subject | One-pot | en |
dc.subject | Organocatalysis | en |
dc.subject | Retro-aldol | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Organocatalytic chemoselective primary alcohol oxidation and subsequent cleavage of lignin model compounds and lignin | en |
dc.type | Journal article | en |
dc.contributor.sponsor | Marie Curie Fellowships | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1002/cssc.201700703 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2018-06-14 | |
dc.identifier.url | http://onlinelibrary.wiley.com/doi/10.1002/cssc.201700703/full#footer-support-info | en |
dc.identifier.grantnumber | SUBICAT | en |
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