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dc.contributor.authorVornholt, Simon M.
dc.contributor.authorHenkelis, Susan E.
dc.contributor.authorMorris, Russell E.
dc.identifier.citationVornholt , S M , Henkelis , S E & Morris , R E 2017 , ' Low temperature synthesis study of metal-organic framework CPO-27 : investigating metal, solvent and base effects down to -78 °C ' , Dalton Transactions , vol. 46 , no. 25 , pp. 8298-8303 .
dc.identifier.otherPURE: 250361556
dc.identifier.otherPURE UUID: 9966a657-9573-470d-99ec-168bff7a427e
dc.identifier.otherBibtex: urn:a7eb73573fcd041e8cf69b35541d3bed
dc.identifier.otherScopus: 85021751534
dc.identifier.otherWOS: 000404467500035
dc.identifier.otherORCID: /0000-0001-7809-0315/work/61622117
dc.descriptionWe thank the EPSRC (EP/K005499/1) (EP/K503162/1) for their financial support of this project and the EPSRC Capital for Great Technologies (EP/L017008/1).en
dc.description.abstractCPO-27-M (M = Co, Mg, Ni, Zn) metal-organic frameworks have been successfully synthesized at temperatures down to -78 °C in a range of solvent systems and their crystallinity and morphology analyzed by powder X-ray diffraction and scanning electron microscopy. CPO-27-Mg and -Zn could be synthesized at lower temperatures using MeOH-NaOH as the solvent with CPO-27-Zn showing the most crystalline material at -78 °C. CPO-27-Zn afforded the most crystalline samples of all studies in MeOH-TEA. However, in MeOH a non-porous monomeric [Zn(H2dhtp)(H2O)2] complex was formed when no base was present. In THF with base (NaOH, TEA) the reaction produced crystalline MOFs in a controlled and stable manner at low temperatures, whilst the reagents were insoluble in THF at low temperature when no base was present. SEM was used to analyze the morphologies of the products.
dc.relation.ispartofDalton Transactionsen
dc.rightsCopyright © 2017, The Royal Society of Chemistry. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at 10.1039/C7DT01223Cen
dc.subjectQD Chemistryen
dc.titleLow temperature synthesis study of metal-organic framework CPO-27 : investigating metal, solvent and base effects down to -78 °Cen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.description.statusPeer revieweden

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