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A magnetisation and Mössbauer study of triazole (M1-x2+Mx3+)M3+F5(Htaz)1-x(taz)x weberites (M = Fe, Co, Mn, Zn, Ga, V)

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Date
28/04/2017
Author
Albino, M.
Clark, L.
Lhoste, J.
Payen, C.
Grenèche, J.-M.
Lightfoot, P.
Maisonneuve, V.
Leblanc, M.
Funder
The Leverhulme Trust
Grant ID
RPG-2013-343
Keywords
QD Chemistry
DAS
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Abstract
A series of triazole fluoride weberites (M1-x2+Mx3+)M3+F5(Htaz)1-x(taz)x is obtained by hydrothermal synthesis. All phases are found to be isostructural to ZnAlF5(Htaz) by powder X-ray diffraction. Weberite structures are prone to induce the magnetic frustration of antiferromagnetic interactions originating from the cationic topology of HTB layers. The (nD) magnetic properties of (0D) Co-Ga, (1D) Zn-Fe, (3D) Fe-Ga, Mn-Fe, Co-Fe and Co-V couples are thus reported. Co2+ or Fe2+ magnetic anisotropy induces a negative magnetisation below TN and compensation temperatures for Mn-Fe and Co-Fe couples. All iron 3D magnetic phases exhibit high Néel temperatures, between 81 K and 102 K, and large |θP/TN| ratios, signalling strong magnetic frustration. Their cation site occupancies and the deduced (de)protonation states of the amine are accurately determined by 57Fe Mössbauer spectrometry. In addition, this spectroscopy evidences a subtle effect of the atmosphere that surrounds the samples: the magnetic ordering temperatures TN decrease significantly when the samples are cooled under vacuum with respect to samples that are cooled at ambient pressure. This novel phenomenon, which is highlighted for all studied (3D) triazole iron weberites, is reversible, and thus provides promising perspectives for understanding the underlying mechanism.
Citation
Albino , M , Clark , L , Lhoste , J , Payen , C , Grenèche , J-M , Lightfoot , P , Maisonneuve , V & Leblanc , M 2017 , ' A magnetisation and Mössbauer study of triazole (M 1-x 2+ M x 3+ )M 3+ F 5 (H taz ) 1-x ( taz ) x weberites (M = Fe, Co, Mn, Zn, Ga, V) ' , Dalton Transactions , vol. 46 , no. 16 , pp. 5352-5362 . https://doi.org/10.1039/C7DT00587C
Publication
Dalton Transactions
Status
Peer reviewed
DOI
https://doi.org/10.1039/C7DT00587C
ISSN
1477-9226
Type
Journal article
Rights
© 2017 the Authors. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1039/C7DT00587C
Description
Work at the University of St Andrews was supported by the Leverhulme Trust RPG-2013-343.
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  • University of St Andrews Research
URI
http://hdl.handle.net/10023/12991

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