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Structural study of the coordination behavior of a tetradentate NO3-donor amino alcohol ligand toward a CdII:HgII mixture
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dc.contributor.author | Mardani, Zahra | |
dc.contributor.author | Golsanamlou, Vali | |
dc.contributor.author | Khodavandegar, Saba | |
dc.contributor.author | Moeini, Keyvan | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2018-02-16T09:30:06Z | |
dc.date.available | 2018-02-16T09:30:06Z | |
dc.date.issued | 2017-05-01 | |
dc.identifier | 250526770 | |
dc.identifier | d2a9a911-41f9-4791-b097-c8ae300588e8 | |
dc.identifier | 000402130600003 | |
dc.identifier | 85019167523 | |
dc.identifier | 000402130600003 | |
dc.identifier.citation | Mardani , Z , Golsanamlou , V , Khodavandegar , S , Moeini , K , Slawin , A M Z & Woollins , J D 2017 , ' Structural study of the coordination behavior of a tetradentate NO 3 -donor amino alcohol ligand toward a Cd II :Hg II mixture ' , Zeitschrift für Naturforschung B - A Journal of Chemical Sciences , vol. 72 , no. 5 , pp. 335-340 . https://doi.org/10.1515/znb-2016-0222 | en |
dc.identifier.issn | 0932-0776 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861832 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/59464687 | |
dc.identifier.uri | https://hdl.handle.net/10023/12733 | |
dc.description.abstract | In this work, the reaction of 2,2′,2″-nitrilotriethanol (NTE) with a 1:1 mixture of CdI2 and HgI2 is investigated. The complex [Cd(NTE)2][Hg2(μ-I)2I4] was synthesized and identified by elemental analysis, FT-IR, 1H NMR spectroscopy and single-crystal X-ray diffraction. The structure of the [HNTE]Cl salt is also presented. In the crystal structure of the complex, the cadmium atom has a CdN2O6 environment in a slightly distorted cube geometry. This geometry is one of the rare cube geometries with a minimum distortion among the Cambridge Structural Database structures for cadmium complexes. The anionic moiety has a binuclear structure with the mercury atoms being in tetrahedral environments. In the network of the complex, in addition to O−H · · · I hydrogen bonds, there are I · · · I interactions which lead to ten-membered rings. | |
dc.format.extent | 6 | |
dc.format.extent | 428520 | |
dc.language.iso | eng | |
dc.relation.ispartof | Zeitschrift für Naturforschung B - A Journal of Chemical Sciences | en |
dc.subject | Amino alcohol | en |
dc.subject | Cd/Hg mixed-metal complex | en |
dc.subject | Coordination behavior | en |
dc.subject | Cube geometry | en |
dc.subject | X-ray crystal structure | en |
dc.subject | Crystal-structures | en |
dc.subject | Cadmium | en |
dc.subject | Complexes | en |
dc.subject | Metal | en |
dc.subject | Mercury(II) | en |
dc.subject | Geometries | en |
dc.subject | Template | en |
dc.subject | Polymer | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Structural study of the coordination behavior of a tetradentate NO3-donor amino alcohol ligand toward a CdII:HgII mixture | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | https://doi.org/10.1515/znb-2016-0222 | |
dc.description.status | Peer reviewed | en |
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