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Chemoselective boronic ester synthesis via controlled speciation
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| dc.contributor.author | Fyfe, James W. B. | |
| dc.contributor.author | Seath, Ciaran P. | |
| dc.contributor.author | Watson, Allan J. B. | |
| dc.date.accessioned | 2018-02-07T10:30:19Z | |
| dc.date.available | 2018-02-07T10:30:19Z | |
| dc.date.issued | 2014-11-03 | |
| dc.identifier | 252192809 | |
| dc.identifier | c3e9d2f2-103b-4045-a968-dd636cc552be | |
| dc.identifier | 84911460873 | |
| dc.identifier.citation | Fyfe , J W B , Seath , C P & Watson , A J B 2014 , ' Chemoselective boronic ester synthesis via controlled speciation ' , Angewandte Chemie International Edition , vol. 53 , no. 45 , pp. 12077-12080 . https://doi.org/10.1002/anie.201406714 | en |
| dc.identifier.issn | 1433-7851 | |
| dc.identifier.other | RIS: urn:F4B934C8EA50600D340EA70F7D098944 | |
| dc.identifier.other | ORCID: /0000-0002-1582-4286/work/56639175 | |
| dc.identifier.uri | https://hdl.handle.net/10023/12683 | |
| dc.description.abstract | Control of boronic acid solution speciation is presented as a new strategy for the chemoselective synthesis of boronic esters. Manipulation of the solution equilibria within a cross-coupling milieu enables the formal homologation of aryl and alkenyl boronic acid pinacol esters. The generation of a new, reactive boronic ester in the presence of an active Pd catalyst also facilitates streamlined iterative catalytic C—C bond formation and provides a method for the controlled oligomerization of sp2-hybridized boronic esters. | |
| dc.format.extent | 4 | |
| dc.format.extent | 478019 | |
| dc.language.iso | eng | |
| dc.relation.ispartof | Angewandte Chemie International Edition | en |
| dc.subject | Chemoselectivity | en |
| dc.subject | Boron | en |
| dc.subject | Boronic acid solution speciation | en |
| dc.subject | Cross-coupling | en |
| dc.subject | Palladium | en |
| dc.subject | Boronic ester | en |
| dc.subject | Oligomerization | en |
| dc.subject | QD Chemistry | en |
| dc.subject.lcc | QD | en |
| dc.title | Chemoselective boronic ester synthesis via controlled speciation | en |
| dc.type | Journal article | en |
| dc.contributor.institution | University of St Andrews. School of Chemistry | en |
| dc.identifier.doi | https://doi.org/10.1002/anie.201406714 | |
| dc.description.status | Peer reviewed | en |
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