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STA-20 : an ABC-6 zeotype structure prepared by co-templating and solved via a hypothetical structure database and STEM-ADF imaging
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dc.contributor.author | Turrina, Alessandro | |
dc.contributor.author | Garcia, Raquel | |
dc.contributor.author | Watts, Abigail E. | |
dc.contributor.author | Greer, Heather F. | |
dc.contributor.author | Bradley, Jonathan | |
dc.contributor.author | Zhou, Wuzong | |
dc.contributor.author | Cox, Paul A. | |
dc.contributor.author | Shannon, Mervyn D. | |
dc.contributor.author | Mayoral, Alvaro | |
dc.contributor.author | Casci, John | |
dc.contributor.author | Wright, Paul A. | |
dc.date.accessioned | 2018-02-06T00:31:31Z | |
dc.date.available | 2018-02-06T00:31:31Z | |
dc.date.issued | 2017-03-14 | |
dc.identifier.citation | Turrina , A , Garcia , R , Watts , A E , Greer , H F , Bradley , J , Zhou , W , Cox , P A , Shannon , M D , Mayoral , A , Casci , J & Wright , P A 2017 , ' STA-20 : an ABC-6 zeotype structure prepared by co-templating and solved via a hypothetical structure database and STEM-ADF imaging ' , Chemistry of Materials , vol. 29 , no. 5 , pp. 2180-2190 . https://doi.org/10.1021/acs.chemmater.6b04892 | en |
dc.identifier.issn | 0897-4756 | |
dc.identifier.other | PURE: 249097752 | |
dc.identifier.other | PURE UUID: e30c7716-762c-4395-a879-1bf332bd35e9 | |
dc.identifier.other | Scopus: 85015453378 | |
dc.identifier.other | ORCID: /0000-0001-9752-7076/work/58055051 | |
dc.identifier.other | WOS: 000396639400031 | |
dc.identifier.other | ORCID: /0000-0002-4243-9957/work/62668293 | |
dc.identifier.uri | https://hdl.handle.net/10023/12672 | |
dc.description | This work has been supported by Johnson Matthey PLC, UK. AEW acknowledges funding from an EPSRC/Johnson Matthey Industrial CASE PhD award EP/N50936X/1. We acknowledge Diamond Light Source for time on beamline I11 under the funded Proposal EE11830-1. | en |
dc.description.abstract | A microporous silicoaluminophosphate with a novel topology type, STA-20, has been prepared via a dual templating method using hexamethylene bisdiazabicyclooctane (diDABCO-C6) and trimethylamine as co-templates. Its structure has been solved and confirmed using a multi-technique approach that included the use of a hypothetical zeolite database to obtain a candidate starting structure, followed by scanning transmission electron microscopy with annular dark field imaging and Rietveld refinement. STA-20 is a member of the ABC-6 family of zeotype structures. The structure has trigonal symmetry, P-31c, with a = 13.15497(18) Å and c = 30.5833(4) Å in the calcined form. It has a 12-layer stacking sequence of 6-rings (6Rs), AABAABAACAAC(A), which contains single and double 6R units. As well as d6r, can and gme cages, STA-20 possesses the longest cage observed in an ordered ABC-6 material, giving a 3D-connected pore system limited by 8R windows. Models for the location of the templates within cages of the framework were obtained by combining elemental analysis, 13C MAS NMR, computer modelling and Rietveld refinement. | |
dc.format.extent | 11 | |
dc.language.iso | eng | |
dc.relation.ispartof | Chemistry of Materials | en |
dc.rights | Copyright © 2017 American Chemical Society. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1021/acs.chemmater.6b04892 | en |
dc.rights | Copyright © 2017 American Chemical Society. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1021/acs.chemmater.6b04892 | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject | BDC | en |
dc.subject.lcc | QD | en |
dc.title | STA-20 : an ABC-6 zeotype structure prepared by co-templating and solved via a hypothetical structure database and STEM-ADF imaging | en |
dc.type | Journal article | en |
dc.description.version | Postprint | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1021/acs.chemmater.6b04892 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2018-02-05 |
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