Reactions of dimethylether in single crystals of the silicoaluminophosphate STA-7 studied via Operando synchrotron infrared microspectroscopy
MetadataShow full item record
Synchrotron infrared micro-spectroscopy has been applied to measure in situ the reaction of dimethylether in single crystals of the silicoaluminophosphate STA-7. The crystals are found to contain a uniform and homogeneous distribution of acidic hydroxyl groups. Dimethylether is hydrogen bonded to the hydroxyl groups at low temperatures, but evidence is found for dissociation to form surface methoxy groups above 473 K, and aromatic hydrocarbon pool species above 573 K. From time resolved infrared measurements coupled with MS analysis of evolved products it is concluded that alkene formation occurs via a direct mechanism from reaction of dimethylether with surface methoxy groups.
Howe , R F , Suwardiyanto , , Price , D J , Castro , M , Wright , P A , Greenaway , A , Frogley , M D & Cinque , G 2018 , ' Reactions of dimethylether in single crystals of the silicoaluminophosphate STA-7 studied via Operando synchrotron infrared microspectroscopy ' , Topics in Catalysis , vol. 61 , no. 3-4 , pp. 199-212 . https://doi.org/10.1007/s11244-018-0890-9
Topics in Catalysis
© The Author(s) 2018. Open Access. This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
DescriptionFinancial support from the EPSRC Catalysis Hub (Suwardiyanto) and an Industrial CASE Award (EPSRC/BP Chemicals) (Price) are also acknowledged.
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.