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Electronic and bite angle effects in catalytic C-O bond cleavage of a lignin model compound using ruthenium xantphos complexes
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dc.contributor.author | Shaw, Luke | |
dc.contributor.author | Somisara, D. M. Upulani K. | |
dc.contributor.author | How, Rebecca C. | |
dc.contributor.author | Westwood, Nicholas J. | |
dc.contributor.author | Bruijnincx, Pieter C. A. | |
dc.contributor.author | Weckhuysen, Bert M. | |
dc.contributor.author | Kamer, Paul C. J. | |
dc.date.accessioned | 2018-01-13T00:31:52Z | |
dc.date.available | 2018-01-13T00:31:52Z | |
dc.date.issued | 2017-02-07 | |
dc.identifier.citation | Shaw , L , Somisara , D M U K , How , R C , Westwood , N J , Bruijnincx , P C A , Weckhuysen , B M & Kamer , P C J 2017 , ' Electronic and bite angle effects in catalytic C-O bond cleavage of a lignin model compound using ruthenium xantphos complexes ' , Catalysis Science & Technology , vol. 7 , no. 3 , pp. 619-626 . https://doi.org/10.1039/C6CY00518G | en |
dc.identifier.issn | 2044-4753 | |
dc.identifier.other | PURE: 248973094 | |
dc.identifier.other | PURE UUID: 04a13a8a-e709-4280-93ed-5cb411380f7b | |
dc.identifier.other | Scopus: 85026905903 | |
dc.identifier.other | ORCID: /0000-0003-0630-0138/work/56424208 | |
dc.identifier.other | WOS: 000398053000009 | |
dc.identifier.uri | https://hdl.handle.net/10023/12471 | |
dc.description | The authors would like to thank the EPSRC (Global Engagement grant EP/K00445X/1 and critical mass grant EP/J018139/1) and the European Union (Marie Curie ITN ‘SuBiCat’ PITN-GA-2013-607044) for financial support. NMSF-Swansea and Mr. Stephen Boyer are kindly acknowledged for mass spectrometry and elemental analysis, respectively. | en |
dc.description.abstract | Bite angle and electronic effects on the ruthenium-diphosphine catalysed ether bond cleavage of the lignin β-O-4 model compound 2-phenoxy-1-phenethanol were tested. Enhanced conversion of the substrate was observed with increasing σ-donor capacity of the ligands. Kinetic and thermodynamic data suggest oxidative addition of the dehydrogenated model compound to the diphosphine Ru(0) complex to be rate-limiting. | |
dc.format.extent | 8 | |
dc.language.iso | eng | |
dc.relation.ispartof | Catalysis Science & Technology | en |
dc.rights | © 2017 the Authors. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1039/C6CY00518G | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Electronic and bite angle effects in catalytic C-O bond cleavage of a lignin model compound using ruthenium xantphos complexes | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Biomedical Sciences Research Complex | en |
dc.identifier.doi | https://doi.org/10.1039/C6CY00518G | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2018-01-12 | |
dc.identifier.url | http://www.rsc.org/suppdata/c6/cy/c6cy00518g/c6cy00518g1.pdf | en |
dc.identifier.grantnumber | EP/J018139/1 | en |
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