Files in this item
Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn)
Item metadata
dc.contributor.author | McCormick, Laura J. | |
dc.contributor.author | Morris, Samuel A. | |
dc.contributor.author | Teat, Simon J. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Morris, Russell E. | |
dc.date.accessioned | 2018-01-03T17:30:06Z | |
dc.date.available | 2018-01-03T17:30:06Z | |
dc.date.issued | 2017-12-24 | |
dc.identifier.citation | McCormick , L J , Morris , S A , Teat , S J , Slawin , A M Z & Morris , R E 2017 , ' Solvent dependent disorder in M 2 (BzOip) 2 (H2O)· solvate (M = Co or Zn) ' , Crystals , vol. 8 , no. 1 . https://doi.org/10.3390/cryst8010006 | en |
dc.identifier.issn | 2073-4352 | |
dc.identifier.other | PURE: 251704139 | |
dc.identifier.other | PURE UUID: e09b6a8d-cdbb-43b2-accb-b6eebda74391 | |
dc.identifier.other | Scopus: 85042092955 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861340 | |
dc.identifier.other | ORCID: /0000-0001-7809-0315/work/61622054 | |
dc.identifier.other | WOS: 000424109000006 | |
dc.identifier.uri | https://hdl.handle.net/10023/12415 | |
dc.description | Funding: British Heart Foundation (NH/11/8/29253) and the UK EPSRC (EP/K005499/1 and EP/K039210/1). | en |
dc.description.abstract | Coordination polymers derived from 5-benzyloxy isophthalic acid (H2BzOip) are rare, with only three reported that do not contain additional bridging ligands, of which two M2(BzOip)2(H2O) (M = Co and Zn) are isomorphous. It was hoped that by varying the solvent system in a reaction between H2BzOip and M(OAc)2 (M = Co and Zn), from water to a water/alcohol mixture, coordination polymers of different topology could be formed. Instead, two polymorphs of the existing M2(BzOip)2(H2O) (M = Co and Zn) were isolated from aqueous methanol and aqueous ethanol, in which a small number of guest solvent molecules are present in the crystals. These guest water molecules disrupt the hexaphenyl embrace motif, leading to varying degrees of disorder of the benzyl groups. | |
dc.language.iso | eng | |
dc.relation.ispartof | Crystals | en |
dc.rights | © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). | en |
dc.subject | Xray crystallography | en |
dc.subject | Solvothermal | en |
dc.subject | Polymorph | en |
dc.subject | Disorder | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn) | en |
dc.type | Journal article | en |
dc.contributor.sponsor | British Council | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.3390/cryst8010006 | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | NH/11/8/29253 | en |
dc.identifier.grantnumber | EP/K005499/1 | en |
dc.identifier.grantnumber | EP/K039210/1 | en |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.