Show simple item record

Files in this item

Thumbnail

Item metadata

dc.contributor.authorMcCormick, Laura J.
dc.contributor.authorMorris, Samuel A.
dc.contributor.authorTeat, Simon J.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorMorris, Russell E.
dc.date.accessioned2018-01-03T17:30:06Z
dc.date.available2018-01-03T17:30:06Z
dc.date.issued2017-12-24
dc.identifier.citationMcCormick , L J , Morris , S A , Teat , S J , Slawin , A M Z & Morris , R E 2017 , ' Solvent dependent disorder in M 2 (BzOip) 2 (H2O)· solvate (M = Co or Zn) ' Crystals , vol. 8 , no. 1 . https://doi.org/10.3390/cryst8010006en
dc.identifier.issn2073-4352
dc.identifier.otherPURE: 251704139
dc.identifier.otherPURE UUID: e09b6a8d-cdbb-43b2-accb-b6eebda74391
dc.identifier.otherScopus: 85042092955
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861340
dc.identifier.urihttp://hdl.handle.net/10023/12415
dc.descriptionFunding: British Heart Foundation (NH/11/8/29253) and the UK EPSRC (EP/K005499/1 and EP/K039210/1).en
dc.description.abstractCoordination polymers derived from 5-benzyloxy isophthalic acid (H2BzOip) are rare, with only three reported that do not contain additional bridging ligands, of which two M2(BzOip)2(H2O) (M = Co and Zn) are isomorphous. It was hoped that by varying the solvent system in a reaction between H2BzOip and M(OAc)2 (M = Co and Zn), from water to a water/alcohol mixture, coordination polymers of different topology could be formed. Instead, two polymorphs of the existing M2(BzOip)2(H2O) (M = Co and Zn) were isolated from aqueous methanol and aqueous ethanol, in which a small number of guest solvent molecules are present in the crystals. These guest water molecules disrupt the hexaphenyl embrace motif, leading to varying degrees of disorder of the benzyl groups.
dc.language.isoeng
dc.relation.ispartofCrystalsen
dc.rights© 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).en
dc.subjectXray crystallographyen
dc.subjectSolvothermalen
dc.subjectPolymorphen
dc.subjectDisorderen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleSolvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn)en
dc.typeJournal articleen
dc.description.versionPreprinten
dc.description.versionPostprinten
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.3390/cryst8010006
dc.description.statusPeer revieweden


This item appears in the following Collection(s)

Show simple item record