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dc.contributor.authorLu, Y. F.
dc.contributor.authorKono, H.
dc.contributor.authorLarkin, T. I.
dc.contributor.authorRost, A. W.
dc.contributor.authorTakayama, T.
dc.contributor.authorBoris, A. V.
dc.contributor.authorKeimer, B.
dc.contributor.authorTakagi, H.
dc.date.accessioned2017-12-19T15:30:07Z
dc.date.available2017-12-19T15:30:07Z
dc.date.issued2017-02-16
dc.identifier.citationLu , Y F , Kono , H , Larkin , T I , Rost , A W , Takayama , T , Boris , A V , Keimer , B & Takagi , H 2017 , ' Zero-gap semiconductor to excitonic insulator transition in Ta 2 NiSe 5 ' , Nature Communications , vol. 8 , 14408 . https://doi.org/10.1038/ncomms14408en
dc.identifier.issn2041-1723
dc.identifier.otherPURE: 251803111
dc.identifier.otherPURE UUID: 59763ca0-8bc5-4de4-a141-36d0947f1a80
dc.identifier.otherWOS: 000394225500001
dc.identifier.otherScopus: 85013150846
dc.identifier.urihttp://hdl.handle.net/10023/12357
dc.descriptionThis work was partially supported by Grant-in-Aid for Scientific Research (S; grant no. 24224010) and by Grant-in-Aid for Scientific Research on Innovative Areas (grant no. JP15H05852). H.T. acknowledges support from the Alexander von Humboldt foundation.en
dc.description.abstractThe excitonic insulator is a long conjectured correlated electron phase of narrow-gap semiconductors and semimetals, driven by weakly screened electron–hole interactions. Having been proposed more than 50 years ago, conclusive experimental evidence for its existence remains elusive. Ta2NiSe5 is a narrow-gap semiconductor with a small one-electron bandgap EG of <50 meV. Below TC=326 K, a putative excitonic insulator is stabilized. Here we report an optical excitation gap Eop ∼0.16 eV below TC comparable to the estimated exciton binding energy EB. Specific heat measurements show the entropy associated with the transition being consistent with a primarily electronic origin. To further explore this physics, we map the TC–EG phase diagram tuning EG via chemical and physical pressure. The dome-like behaviour around EG∼0 combined with our transport, thermodynamic and optical results are fully consistent with an excitonic insulator phase in Ta2NiSe5.
dc.format.extent7
dc.language.isoeng
dc.relation.ispartofNature Communicationsen
dc.rights© The Author(s) 2017. This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/en
dc.subjectQC Physicsen
dc.subjectNDASen
dc.subjectBDCen
dc.subjectR2Cen
dc.subject.lccQCen
dc.titleZero-gap semiconductor to excitonic insulator transition in Ta2NiSe5en
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Physics and Astronomyen
dc.identifier.doihttps://doi.org/10.1038/ncomms14408
dc.description.statusPeer revieweden


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