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Synthesis and characterization of heterobimetallic complexes with pyridyl selenolato ligands. Crystal structure of [{Pt(C5H4N)(SeC5H4N)(dppp)}ZnCl2]
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dc.contributor.author | Chauhan, Rohit Singh | |
dc.contributor.author | Shivran, Neelam | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2017-12-17T00:32:13Z | |
dc.date.available | 2017-12-17T00:32:13Z | |
dc.date.issued | 2017-02-15 | |
dc.identifier | 248189401 | |
dc.identifier | cc583db2-68b0-4bd6-bc99-bf840bd695cb | |
dc.identifier | 85007362335 | |
dc.identifier | 000394473200024 | |
dc.identifier.citation | Chauhan , R S , Shivran , N , Slawin , A M Z & Woollins , J D 2017 , ' Synthesis and characterization of heterobimetallic complexes with pyridyl selenolato ligands. Crystal structure of [{Pt(C 5 H 4 N)(SeC 5 H 4 N)(dppp)}ZnCl 2 ] ' , Journal of Organometallic Chemistry , vol. 830 , pp. 181-187 . https://doi.org/10.1016/j.jorganchem.2016.12.013 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861994 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779150 | |
dc.identifier.uri | https://hdl.handle.net/10023/12346 | |
dc.description | One of the authors (RSC) is grateful to DST for the financial support under the DST young scientist scheme YSS/2014/000797. | en |
dc.description.abstract | Reactions of [Pt(SeC5H4N)2(P∩P)] with M(OAc)2.2H2O/MX2 (P∩P = dppm, dppp; M = Zn, Cd, Hg, Cu; X = Cl) resulted various products depend upon the nature of the phosphine. In case of dppm, reaction between [Pt(SeC5H4N)2(dppm)] and M(OAc)2.2H2O/MX2 (M = Zn, Cd, Hg) afforded an exchange product of composition [PtCl2(dppm)]. Similarly, the reaction with ‘dppp’ analog yielded an adduct [{Pt(SeC5H4N)2(dppp)}MX2] (M = Cd, Hg, Cu; X = Cl, OAc). Whereas, reaction with Zn(OAc)2, on extraction with dichloromethane resulted the product with the loss of one selenium atom of composition [{Pt(C5H4N)(SeC5H4N)(dppp)}ZnCl2]. These complexes were characterized by elemental analyses and NMR (1H, 31P, 77Se, 195Pt) spectroscopy. The molecular structure of [{Pt(C5H4N)(SeC5H4N)(dppp)}ZnCl2] was established by single crystal X-ray diffraction analyses. | |
dc.format.extent | 7 | |
dc.format.extent | 845806 | |
dc.format.extent | 917639 | |
dc.language.iso | eng | |
dc.relation.ispartof | Journal of Organometallic Chemistry | en |
dc.subject | Platinum | en |
dc.subject | Selenolate | en |
dc.subject | NMR | en |
dc.subject | X-ray | en |
dc.subject | Phosphines | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Synthesis and characterization of heterobimetallic complexes with pyridyl selenolato ligands. Crystal structure of [{Pt(C5H4N)(SeC5H4N)(dppp)}ZnCl2] | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | 10.1016/j.jorganchem.2016.12.013 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2017-12-16 | |
dc.identifier.url | http://www.sciencedirect.com/science/article/pii/S0022328X16305654#sec5 | en |
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