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dc.contributor.authorChauhan, Rohit Singh
dc.contributor.authorShivran, Neelam
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2017-12-17T00:32:13Z
dc.date.available2017-12-17T00:32:13Z
dc.date.issued2017-02-15
dc.identifier248189401
dc.identifiercc583db2-68b0-4bd6-bc99-bf840bd695cb
dc.identifier85007362335
dc.identifier000394473200024
dc.identifier.citationChauhan , R S , Shivran , N , Slawin , A M Z & Woollins , J D 2017 , ' Synthesis and characterization of heterobimetallic complexes with pyridyl selenolato ligands. Crystal structure of [{Pt(C 5 H 4 N)(SeC 5 H 4 N)(dppp)}ZnCl 2 ] ' , Journal of Organometallic Chemistry , vol. 830 , pp. 181-187 . https://doi.org/10.1016/j.jorganchem.2016.12.013en
dc.identifier.issn0022-328X
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861994
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779150
dc.identifier.urihttps://hdl.handle.net/10023/12346
dc.descriptionOne of the authors (RSC) is grateful to DST for the financial support under the DST young scientist scheme YSS/2014/000797.en
dc.description.abstractReactions of [Pt(SeC5H4N)2(P∩P)] with M(OAc)2.2H2O/MX2 (P∩P = dppm, dppp; M = Zn, Cd, Hg, Cu; X = Cl) resulted various products depend upon the nature of the phosphine. In case of dppm, reaction between [Pt(SeC5H4N)2(dppm)] and M(OAc)2.2H2O/MX2 (M = Zn, Cd, Hg) afforded an exchange product of composition [PtCl2(dppm)]. Similarly, the reaction with ‘dppp’ analog yielded an adduct [{Pt(SeC5H4N)2(dppp)}MX2] (M = Cd, Hg, Cu; X = Cl, OAc). Whereas, reaction with Zn(OAc)2, on extraction with dichloromethane resulted the product with the loss of one selenium atom of composition [{Pt(C5H4N)(SeC5H4N)(dppp)}ZnCl2]. These complexes were characterized by elemental analyses and NMR (1H, 31P, 77Se, 195Pt) spectroscopy. The molecular structure of [{Pt(C5H4N)(SeC5H4N)(dppp)}ZnCl2] was established by single crystal X-ray diffraction analyses.
dc.format.extent7
dc.format.extent845806
dc.format.extent917639
dc.language.isoeng
dc.relation.ispartofJournal of Organometallic Chemistryen
dc.subjectPlatinumen
dc.subjectSelenolateen
dc.subjectNMRen
dc.subjectX-rayen
dc.subjectPhosphinesen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleSynthesis and characterization of heterobimetallic complexes with pyridyl selenolato ligands. Crystal structure of [{Pt(C5H4N)(SeC5H4N)(dppp)}ZnCl2]en
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doi10.1016/j.jorganchem.2016.12.013
dc.description.statusPeer revieweden
dc.date.embargoedUntil2017-12-16
dc.identifier.urlhttp://www.sciencedirect.com/science/article/pii/S0022328X16305654#sec5en


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