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Synthesis and structural study of novel selenation derivatives of N, N-Dialkylcyanamides
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dc.contributor.author | Hua, Guoxiong | |
dc.contributor.author | Du, Junyi | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2017-12-17T00:32:08Z | |
dc.date.available | 2017-12-17T00:32:08Z | |
dc.date.issued | 2016-12-21 | |
dc.identifier | 248128225 | |
dc.identifier | 27482b50-8ef9-4589-820e-5a3de35ee247 | |
dc.identifier | 85041917354 | |
dc.identifier | 000395433600027 | |
dc.identifier.citation | Hua , G , Du , J , Slawin , A M Z & Woollins , J D 2016 , ' Synthesis and structural study of novel selenation derivatives of N, N -Dialkylcyanamides ' , ChemistrySelect , vol. 1 , no. 21 , pp. 6810-6817 . https://doi.org/10.1002/slct.201601577 | en |
dc.identifier.issn | 2365-6549 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861829 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779152 | |
dc.identifier.uri | https://hdl.handle.net/10023/12345 | |
dc.description | We are grateful to the University of St Andrews for financial support and the EPSRC National Mass Spectrometry Service Centre (Swansea) for mass spectral measurements. | en |
dc.description.abstract | The reaction of 2,4-bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide {[PhP(Se)(µ-Se)]2, Woollins’ reagent, WR } with N, N-dialkylcyanamides 1–3 in refluxing toluene solution led to the corresponding [2+3] cycloaddition products 4-dialkylamino-2,5-diphenyl-1,3,2,5-selenazadiphosphole 2,5-diselenides 4–6 in good yields, the latter were further treated with water resulting in the corresponding hydrolysis derivatives dialkyl-selenoureas 7–9 , and phosphinodiselenoates 10 and 11 . Selenourea 7 could be transferred into 1,3-selenazol-2-amines 12–15 in excellent yields by further cyclization with four different α-haloketones. All new compounds have been characterized by IR spectroscopy, multi-NMR (1H, 13C, 31P, 77Se) spectroscopy and accurate mass measurement. The single crystal X-ray structural features of nine new compounds are also discussed. | |
dc.format.extent | 8 | |
dc.format.extent | 1914169 | |
dc.format.extent | 2294570 | |
dc.language.iso | eng | |
dc.relation.ispartof | ChemistrySelect | en |
dc.subject | Cyanamides | en |
dc.subject | Phosphorus-selenium heteroatom compounds | en |
dc.subject | 1,3-Selenazol-2-amines | en |
dc.subject | Selenoureas | en |
dc.subject | Woollins’ reagent | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Synthesis and structural study of novel selenation derivatives of N, N-Dialkylcyanamides | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | https://doi.org/10.1002/slct.201601577 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2017-12-16 |
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