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dc.contributor.authorBonyhady, Simon J.
dc.contributor.authorHolzmann, Nicole
dc.contributor.authorFrenking, Gernot
dc.contributor.authorStasch, Andreas
dc.contributor.authorJones, Cameron
dc.date.accessioned2017-12-10T00:32:09Z
dc.date.available2017-12-10T00:32:09Z
dc.date.issued2017-07-10
dc.identifier.citationBonyhady , S J , Holzmann , N , Frenking , G , Stasch , A & Jones , C 2017 , ' Synthesis, characterization, and computational analysis of the dialanate dianion, [H 3 Al-AlH 3 ] 2− : a valence isoelectronic analogue of ethane ' Angewandte Chemie International Edition , vol. 56 , no. 29 , pp. 8527-8531 . https://doi.org/10.1002/anie.201610601en
dc.identifier.issn1521-3773
dc.identifier.otherPURE: 248179505
dc.identifier.otherPURE UUID: 9b9364c5-883f-4146-b5e9-f3a1e2ad2ebe
dc.identifier.otherBibtex: urn:5918f23daf56c17b76b8e51f24a792a0
dc.identifier.otherScopus: 85006795638
dc.identifier.urihttp://onlinelibrary.wiley.com/doi/10.1002/anie.201610601/full#footer-support-infoen
dc.descriptionC.J. and A.S. gratefully acknowledge financial support from the Australian Research Council, while C.J. thanks the U.S. Air Force Asian Office of Aerospace Research and Development (FA2386-14-1-4043) for funding. G.F. acknowledges financial support from the Deutsche Forschungsgemeinschaft.en
dc.description.abstractThe first example of a well-defined binary, low-oxidation-state aluminum hydride species that is stable at ambient temperature, namely the dianion in [{(DepNacnac)Mg}2(μ-H)]2[H3Al-AlH3] (DepNacnac=[(DepNCMe)2CH]−, Dep=2,6-diethylphenyl), has been prepared via a magnesium(I) reduction of the alanate complex, (DepNacnac)Mg(μ-H)3AlH(NEt3). An X-ray crystallographic analysis has shown the compound to be a contact ion complex, which computational studies have revealed to be the source of the stability of the aluminum(II) dianion.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofAngewandte Chemie International Editionen
dc.rights© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1002/anie.201610601en
dc.subjectDFT calculationsen
dc.subjectDialanateen
dc.subjectHydrideen
dc.subjectMagnesium(I)en
dc.subjectMetal–metal bondingen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleSynthesis, characterization, and computational analysis of the dialanate dianion, [H3Al-AlH3]2− : a valence isoelectronic analogue of ethaneen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.identifier.doihttps://doi.org/10.1002/anie.201610601
dc.description.statusPeer revieweden
dc.date.embargoedUntil2017-12-09


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