Synthesis, characterization, and computational analysis of the dialanate dianion, [H3Al-AlH3]2− : a valence isoelectronic analogue of ethane

Bonyhady, Simon J.; Holzmann, Nicole; Frenking, Gernot; Stasch, Andreas; Jones, Cameron

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dc.contributor.author	Bonyhady, Simon J.
dc.contributor.author	Holzmann, Nicole
dc.contributor.author	Frenking, Gernot
dc.contributor.author	Stasch, Andreas
dc.contributor.author	Jones, Cameron
dc.date.accessioned	2017-12-10T00:32:09Z
dc.date.available	2017-12-10T00:32:09Z
dc.date.issued	2017-07-10
dc.identifier	248179505
dc.identifier	9b9364c5-883f-4146-b5e9-f3a1e2ad2ebe
dc.identifier	85006795638
dc.identifier	000404739200039
dc.identifier.citation	Bonyhady , S J , Holzmann , N , Frenking , G , Stasch , A & Jones , C 2017 , ' Synthesis, characterization, and computational analysis of the dialanate dianion, [H 3 Al-AlH 3 ] 2− : a valence isoelectronic analogue of ethane ' , Angewandte Chemie International Edition , vol. 56 , no. 29 , pp. 8527-8531 . https://doi.org/10.1002/anie.201610601	en
dc.identifier.issn	1521-3773
dc.identifier.other	Bibtex: urn:5918f23daf56c17b76b8e51f24a792a0
dc.identifier.other	ORCID: /0000-0002-7407-8287/work/58055906
dc.identifier.uri	https://hdl.handle.net/10023/12306
dc.description	C.J. and A.S. gratefully acknowledge financial support from the Australian Research Council, while C.J. thanks the U.S. Air Force Asian Office of Aerospace Research and Development (FA2386-14-1-4043) for funding. G.F. acknowledges financial support from the Deutsche Forschungsgemeinschaft.	en
dc.description.abstract	The first example of a well-defined binary, low-oxidation-state aluminum hydride species that is stable at ambient temperature, namely the dianion in [{(DepNacnac)Mg}2(μ-H)]2[H3Al-AlH3] (DepNacnac=[(DepNCMe)2CH]−, Dep=2,6-diethylphenyl), has been prepared via a magnesium(I) reduction of the alanate complex, (DepNacnac)Mg(μ-H)3AlH(NEt3). An X-ray crystallographic analysis has shown the compound to be a contact ion complex, which computational studies have revealed to be the source of the stability of the aluminum(II) dianion.
dc.format.extent	5
dc.format.extent	250207
dc.language.iso	eng
dc.relation.ispartof	Angewandte Chemie International Edition	en
dc.subject	DFT calculations	en
dc.subject	Dialanate	en
dc.subject	Hydride	en
dc.subject	Magnesium(I)	en
dc.subject	Metal–metal bonding	en
dc.subject	QD Chemistry	en
dc.subject	NDAS	en
dc.subject.lcc	QD	en
dc.title	Synthesis, characterization, and computational analysis of the dialanate dianion, [H3Al-AlH3]2− : a valence isoelectronic analogue of ethane	en
dc.type	Journal article	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.identifier.doi	https://doi.org/10.1002/anie.201610601
dc.description.status	Peer reviewed	en
dc.date.embargoedUntil	2017-12-09
dc.identifier.url	http://onlinelibrary.wiley.com/doi/10.1002/anie.201610601/full#footer-support-info	en

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