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dc.contributor.authorAnderson, Amanda E.
dc.contributor.authorBaddeley, Christopher J.
dc.contributor.authorWright, Paul A.
dc.date.accessioned2017-11-30T13:30:05Z
dc.date.available2017-11-30T13:30:05Z
dc.date.issued2017-11-27
dc.identifier.citationAnderson , A E , Baddeley , C J & Wright , P A 2017 , ' Tuning Pd-nanoparticle@MIL-101(Cr) catalysts for tandem reductive amination ' , Catalysis Letters , vol. In press . https://doi.org/10.1007/s10562-017-2208-0en
dc.identifier.issn1011-372X
dc.identifier.otherPURE: 251447280
dc.identifier.otherPURE UUID: 7e33ce4d-b71c-4d21-a3bc-5e729a57ddc9
dc.identifier.otherScopus: 85035134902
dc.identifier.otherORCID: /0000-0001-9750-6494/work/57330774
dc.identifier.otherORCID: /0000-0002-4243-9957/work/62668254
dc.identifier.urihttp://hdl.handle.net/10023/12204
dc.descriptionThe authors thank the EPSRC (EP/L505079/1), SASOL Technology UK and the University of St Andrews for funding.en
dc.description.abstractThe versatility of MOFs as highly porous Lewis acidic supports for precious metal nanoparticles has been exploited for one-pot tandem reductive amination catalysis. MIL-101(Cr) loaded with Pd nanoparticles ca. 3 nm in size at 0.2–1 wt% has been used to catalyse the reaction of 4′-fluoroacetophenone with benzylamine under 10 bar of H2 to give the secondary amine, 4′-fluoro-α-methyl-N-phenylmethylbenzenemethanamine. For the highest Pd loading, major hydrogenolysis of the secondary amine occurs in a second tandem reaction, but by changing the ratio of Pd to Lewis acidic Cr3+ active sites it is possible to tune the catalytic selectivity to the desired 2° amine product. An empirical kinetic analysis was performed to demonstrate this active site complementarity.
dc.language.isoeng
dc.relation.ispartofCatalysis Lettersen
dc.rights© The Author(s) 2017. This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.en
dc.subjectPd@MIL-101en
dc.subjectTandem reductive aminationen
dc.subjectKinetic modellingen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleTuning Pd-nanoparticle@MIL-101(Cr) catalysts for tandem reductive aminationen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1007/s10562-017-2208-0
dc.description.statusPeer revieweden
dc.identifier.urlhttps://link.springer.com/article/10.1007%2Fs10562-017-2208-0#SupplementaryMaterialen


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