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Alternative hydrogen peroxide sources for peroxyoxalate “glowstick” chemiluminescence demonstrations

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Glowstick_paper_28_10_2016_.pdf (796.0Kb)
Date
10/01/2017
Author
Smellie, Iain A.
Aldred (née Prentis), Joanna K. D.
Bower, Benjamin
Cochrane, Amber
Macfarlane, Laurie
McCarron, Hollie B.
O'Hara, Roxanna
Patterson, Iain
Thomson, Marie I.
Walker, Jessica M.
Keywords
General public
High School/Introductory Chemistry
Demonstrations
Organic chemistry
Public understanding/outreach
Analogies/transfer
Esters
Oxidation/reduction
Phenols
QD Chemistry
NDAS
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Abstract
Simple protocols have been devised for peroxyoxalate chemiluminescence demonstrations that use urea–hydrogen peroxide or sodium percarbonate as oxidants in place of aqueous solutions of hydrogen peroxide. The procedures described are compatible with well-known peroxyoxalates and fluorescers and have been found to be convenient for use for outreach activities in venues with limited laboratory facilities.
Citation
Smellie , I A , Aldred (née Prentis) , J K D , Bower , B , Cochrane , A , Macfarlane , L , McCarron , H B , O'Hara , R , Patterson , I , Thomson , M I & Walker , J M 2017 , ' Alternative hydrogen peroxide sources for peroxyoxalate “glowstick” chemiluminescence demonstrations ' , Journal of Chemical Education , vol. 94 , no. 1 , pp. 112-114 . https://doi.org/10.1021/acs.jchemed.6b00536
Publication
Journal of Chemical Education
Status
Peer reviewed
DOI
https://doi.org/10.1021/acs.jchemed.6b00536
ISSN
0021-9584
Type
Journal article
Rights
Copyright © 2016 The American Chemical Society and Division of Chemical Education, Inc. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1021/acs.jchemed.6b00536
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  • University of St Andrews Research
URL
http://pubs.acs.org/doi/suppl/10.1021/acs.jchemed.6b00536
URI
http://hdl.handle.net/10023/12134

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