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dc.contributor.authorPrytulak, J.
dc.contributor.authorBrett, A.
dc.contributor.authorWebb, M.
dc.contributor.authorPlank, T.
dc.contributor.authorRehkämper, M.
dc.contributor.authorSavage, P. S.
dc.contributor.authorWoodhead, J.
dc.identifier.citationPrytulak , J , Brett , A , Webb , M , Plank , T , Rehkämper , M , Savage , P S & Woodhead , J 2017 , ' Thallium elemental behavior and stable isotope fractionation during magmatic processes ' , Chemical Geology , vol. 448 , pp. 71-83 .
dc.identifier.otherPURE: 247456707
dc.identifier.otherPURE UUID: f513011c-cfb2-4a4d-bdb1-1ce26326d74c
dc.identifier.otherRIS: urn:BC0B890544BDCEB91FBFFBE7F1A25AE0
dc.identifier.otherScopus: 85027958943
dc.identifier.otherWOS: 000393003200005
dc.identifier.otherORCID: /0000-0001-8464-0264/work/64034612
dc.descriptionJP was partly supported by NERC fellowship NE/H01313X/2. AB was supported by a Janet Watson Earth Science and Engineering Departmental PhD studentship and MW was supported in part by an undergraduate research opportunity award from Imperial College London. Trace element analyses were supported from US NSF Grant EAR-1456814 to TP.en
dc.description.abstractStable thallium (Tl) isotopes are an extremely sensitive tracer for the addition of small amounts of sediments or materials altered at low temperatures to the source(s) of mantle-derived melts. The ability of Tl to trace such materials is due to the large concentration contrast between the mantle (Tl < 2 ng/g) and possible exotic inputs (Tl ~ 100 ng/g to > μg/g), which also often display fractionated Tl isotope compositions. However, the magnitude of Tl isotope fractionation induced by igneous processes alone has not been systematically assessed. Here, two suites of co-genetic magmas, spanning a large range of differentiation, from Hekla, Iceland, and Anatahan, in the Mariana arc, are used to assess the behavior of thallium and its stable isotope variations during magmatic processes. Thallium behaves as a near-perfectly incompatible lithophile element throughout magmatic evolution, mirroring elements such as Rb, Cs, and K. Lavas from Hekla have restricted Cs/Tl ratios and stable Tl isotope compositions, which overlap with mantle estimates. Lavas from subduction-related Anatahan volcano also have a restricted range in Tl isotope composition, which overlaps with Hekla and MORB, demonstrating that fractional crystallisation and partial melting does not fractionate stable Tl isotopes. Subduction environments display variable Cs/Tl, indicating that the subduction process commonly fractionates these two elements. The immunity of thallium stable isotopes to fractionation by magmatic processes coupled with its extreme sensitivity for tracing pelagic sediments, FeMn crusts and low temperature altered oceanic crust highlight its value in elucidating the nature of mantle sources of both oceanic basalts and arc lavas. Critically, meaningful interpretation of thallium isotope compositions need not be restricted to primitive lavas.
dc.relation.ispartofChemical Geologyen
dc.rights© 2016 Published by Elsevier B.V. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at:
dc.subjectStable isotopesen
dc.subjectMagmatic differentiationen
dc.subjectGE Environmental Sciencesen
dc.titleThallium elemental behavior and stable isotope fractionation during magmatic processesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews.School of Earth & Environmental Sciencesen
dc.contributor.institutionUniversity of St Andrews.St Andrews Centre for Exoplanet Scienceen
dc.contributor.institutionUniversity of St Andrews.St Andrews Isotope Geochemistryen
dc.contributor.institutionUniversity of St Andrews.Earth and Environmental Sciencesen
dc.description.statusPeer revieweden

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