A novel copper oxalate, Na2Cu(C2O4)2
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A novel copper oxalate Na2Cu(C2O4)2 was synthesized through a hydrothermal method and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic system, P21/n space group with a = 72578(3) Å, b = 5.7711(4) Å, c = 8.6604(8) Å, β = 106.948(9)°. The structure displays a novel stacking pattern of [Cu(C2O4)2]2– units connected through electrostatic attraction by Na+ cations. Structural comparisons are made to related compounds.
Yao , W , Armstrong , A R & Lightfoot , P 2016 , ' A novel copper oxalate, Na 2 Cu(C 2 O 4 ) 2 ' Zeitschrift für Anorganische und Allgemeine Chemie , vol 642 , no. 23 , pp. 1345-1349 . DOI: 10.1002/zaac.201600320
Zeitschrift für Anorganische und Allgemeine Chemie
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1002/zaac.201600320
The authors thank the Royal Society for the award of a Newton Fellowship (NF140881) to W.Y.
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