Show simple item record

Files in this item

Thumbnail

Item metadata

dc.contributor.authorMeigh, Christina B. E.
dc.contributor.authorNejman, Phillip S.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2017-10-28T23:31:57Z
dc.date.available2017-10-28T23:31:57Z
dc.date.issued2017-02-24
dc.identifier247180749
dc.identifierdbe8981e-ebde-4111-b0df-f9c2ae5af461
dc.identifier85027925678
dc.identifier000392682000015
dc.identifier.citationMeigh , C B E , Nejman , P S , Slawin , A M Z & Woollins , J D 2017 , ' Complexation of aromatic dichalcogen ligands to germanium ' , Inorganica Chimica Acta , vol. 456 , pp. 120-127 . https://doi.org/10.1016/j.ica.2016.10.038en
dc.identifier.issn0020-1693
dc.identifier.otherRIS: urn:213E0FE0F50ABDFA2BB6C5F64F0B610E
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861788
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779149
dc.identifier.urihttps://hdl.handle.net/10023/11938
dc.description.abstractEight novel germanium compounds of the type [R2Ge(E-Ar-E)], where R = Me, Ph; E-Ar-E = an aromatic bidentate chalcogen ligand, were successfully synthesised. The effects of changing 3 variables within the series were investigated. These variables included the chalcogen (E = S/Se), aromatic backbone (Ar = Nap/Biphenyl) and R group (Me/Ph) employed. The choice of aromatic backbone had the greatest effect on the structure. A substantial change in geometry around the germanium centre was observed within the solid state structures depending on whether the backbone was naphthalene or biphenyl. This affected the stability of the compound and resulted in the visible decomposition of two selenium complexes over several days. All novel compounds were characterised by multinuclear NMR, IR, mass spectroscopy and single crystal X-ray diffraction.
dc.format.extent8
dc.format.extent1675886
dc.language.isoeng
dc.relation.ispartofInorganica Chimica Actaen
dc.subjectGermaniumen
dc.subjectSulfuren
dc.subjectSeleniumen
dc.subjectCoordinationen
dc.subjectX-Ray structureen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleComplexation of aromatic dichalcogen ligands to germaniumen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doi10.1016/j.ica.2016.10.038
dc.description.statusPeer revieweden
dc.date.embargoedUntil2017-10-28


This item appears in the following Collection(s)

Show simple item record