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Phosphorus-sulfur heterocycles incorporating an O-P(S)-O or O-P(S)-S-S-P(S)-O scaffold : one-pot synthesis and crystal structure study
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dc.contributor.author | Hua, Guoxiong | |
dc.contributor.author | Davidson, Kate | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Du, Junyi | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2017-10-18T09:30:41Z | |
dc.date.available | 2017-10-18T09:30:41Z | |
dc.date.issued | 2017-10-10 | |
dc.identifier | 251316816 | |
dc.identifier | 8ad4c897-0583-47ef-b74c-ca7f5400ef14 | |
dc.identifier | 85032744743 | |
dc.identifier | 000414670600114 | |
dc.identifier.citation | Hua , G , Davidson , K , Cordes , D B , Du , J , Slawin , A M Z & Woollins , J D 2017 , ' Phosphorus-sulfur heterocycles incorporating an O-P(S)-O or O-P(S)-S-S-P(S)-O scaffold : one-pot synthesis and crystal structure study ' , Molecules , vol. 22 , no. 10 , 1687 . https://doi.org/10.3390/molecules22101687 | en |
dc.identifier.issn | 1420-3049 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/37898073 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56862030 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/59464696 | |
dc.identifier.uri | https://hdl.handle.net/10023/11878 | |
dc.description | The authors are grateful to the University of St Andrews for financial support. | en |
dc.description.abstract | A new one-pot preparative route was developed to synthesize novel organophosphorus sulfur heterocycles via the reaction of the four-membered ring thionation reagent [2,4-diferrocenyl 1,3,2,4-diathiadiphosphetane 2,4-disulfide (FcLR, a ferrocene analogue of Lawesson’s reagent)] and alkenyl/aryl-diols and I2 (or SOCl2) in the presence of triethylamine. Therefore, a series of five- to ten-membered heterocycles bearing an O-P(S)-O or an O-P(S)-S-S-P(S)-O linkage were synthesized. The synthesis features a novel application of the multicomponent reaction, providing an efficient and environmentally benign method for the preparation of the unusual phosphorus-sulfur heterocycles. Seven representative X-ray structures confirm the formation of these heterocycles. | |
dc.format.extent | 14 | |
dc.format.extent | 3292514 | |
dc.language.iso | eng | |
dc.relation.ispartof | Molecules | en |
dc.subject | 2,4-Diferrocenyl-1,3,2,4-diathiadiphosphetane 2,4-disulfide | en |
dc.subject | Diols | en |
dc.subject | One-pot reaction | en |
dc.subject | Iodine oxidation | en |
dc.subject | Phosphorus-sulfur heterocycles | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Phosphorus-sulfur heterocycles incorporating an O-P(S)-O or O-P(S)-S-S-P(S)-O scaffold : one-pot synthesis and crystal structure study | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | https://doi.org/10.3390/molecules22101687 | |
dc.description.status | Peer reviewed | en |
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