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Single crystal X-ray structural features of aromatic compounds having a pentafluorosulfuranyl (SF5) functional group
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dc.contributor.author | Du, Junyi | |
dc.contributor.author | Hua, Guoxiong | |
dc.contributor.author | Beier, Petr | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2017-10-04T23:32:24Z | |
dc.date.available | 2017-10-04T23:32:24Z | |
dc.date.issued | 2017-06 | |
dc.identifier | 245780312 | |
dc.identifier | 1833af76-d54b-4ee8-9908-08b85ee9092a | |
dc.identifier | 84990856298 | |
dc.identifier | 000400574100018 | |
dc.identifier.citation | Du , J , Hua , G , Beier , P , Slawin , A M Z & Woollins , J D 2017 , ' Single crystal X-ray structural features of aromatic compounds having a pentafluorosulfuranyl (SF 5 ) functional group ' , Structural Chemistry , vol. 28 , no. 3 , pp. 723-733 . https://doi.org/10.1007/s11224-016-0854-2 | en |
dc.identifier.issn | 1040-0400 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861648 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779156 | |
dc.identifier.uri | https://hdl.handle.net/10023/11803 | |
dc.description | The authors are grateful to the University of St Andrews for financial support. | en |
dc.description.abstract | Nine pentafluorosulfuranyl (SF5)-containing aromatic compounds have been characterized crystallographically. The SF5 group has an umbrella geometry, and the sulfur atom in the SF5 group is in an approximately octahedral coordination environment. All S-F bond lengths [1.572(3) to 1.618(3) Å] are very similar and the C-S-Fax bond angles [178.94(14) to 180°] are very close to each other. The angle of two adjacent Feq is approximate to 90°. The intramolecular and intermolecular interactions such as Caryl-H···Feq, Caryl-H···O/N/F/Cl interactions, and π-stacking interactions play a very important role in their three-dimension packing frameworks. | |
dc.format.extent | 11 | |
dc.format.extent | 1889570 | |
dc.format.extent | 332223 | |
dc.language.iso | eng | |
dc.relation.ispartof | Structural Chemistry | en |
dc.subject | Pentafluorosulfuranyl (SF5) group | en |
dc.subject | Aromatic compounds | en |
dc.subject | Single crystal X-ray structure | en |
dc.subject | Intramolecular interactions | en |
dc.subject | Intermolecular interactions | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Single crystal X-ray structural features of aromatic compounds having a pentafluorosulfuranyl (SF5) functional group | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | 10.1007/s11224-016-0854-2 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2017-10-04 | |
dc.identifier.url | http://link.springer.com/article/10.1007%2Fs11224-016-0854-2#SupplementaryMaterial | en |
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