Show simple item record

Files in this item

Thumbnail
Name:
Cordes_2017_C_AEJ_Homochiral_CCBY_VoR.pdf
Size:
2.449Mb
Format:
PDF
View/Open

Homochiral emissive Λ8- andΔ8-[Ir8Pd4]16+ supramolecular cages

Item metadata

dc.contributor.authorRota Martir, Diego
dc.contributor.authorEscudero, Daniel
dc.contributor.authorJacquemin, Denis
dc.contributor.authorCordes, David
dc.contributor.authorSlawin, Alexandra
dc.contributor.authorFruchtl, Herbert
dc.contributor.authorWarriner, Stuart
dc.contributor.authorZysman-Colman, Eli
dc.date.accessioned2017-09-29T16:30:14Z
dc.date.available2017-09-29T16:30:14Z
dc.date.issued2017-10-12
dc.identifier.citationRota Martir , D , Escudero , D , Jacquemin , D , Cordes , D , Slawin , A , Fruchtl , H , Warriner , S & Zysman-Colman , E 2017 , ' Homochiral emissive Λ 8 - andΔ 8 -[Ir 8 Pd 4 ] 16+ supramolecular cages ' , Chemistry - A European Journal , vol. 23 , no. 57 , pp. 14358–14366 . https://doi.org/10.1002/chem.201703273en
dc.identifier.issn0947-6539
dc.identifier.otherPURE: 250714314
dc.identifier.otherPURE UUID: 8ff2fd0d-9181-4245-84b8-bacb163ba9e2
dc.identifier.otherScopus: 85029212110
dc.identifier.otherORCID: /0000-0002-5366-9168/work/36874684
dc.identifier.otherORCID: /0000-0001-7183-6022/work/56639087
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861651
dc.identifier.otherWOS: 000412819400033
dc.identifier.otherORCID: /0000-0001-6647-4266/work/60887484
dc.identifier.urihttps://hdl.handle.net/10023/11764
dc.descriptionEZ-C acknowledges the University of St Andrews and EPSRC (EP/M02105X/1) for financial support. DE thanks funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No 700961. DJ acknowledges the European Research Council (Marches grant n°278845) and the RFI Lumomat for financial support.en
dc.description.abstractSynthetic self-assembly is a powerful technique for the bottom-up construction of discrete and well-defined polyhedral nanostructures resembling the spherical shape of large biological systems. In recent years, numerous Archimedean-shaped coordination cages have been reported based on the assembly of bent monodentate organic ligands containing two or more distal pyridyl rings and square planar PdII ions. The formation of photoactive PdII metallamacrocycles and cages, however, remain rare. Here we report the first examples of emissive and homochiral supramolecular cages of the form of [Ir8Pd4]16+. These cages provide a suitably sized cavity to host large guest molecules. Importantly, encapsulation and energy transfer have been observed between the blue-emitting NBu4[Ir(dFppy)2(CN)2] guest and the red-emitting Δ8-[Ir8Pd4]16+ cage.
dc.language.isoeng
dc.relation.ispartofChemistry - A European Journalen
dc.rights© 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.en
dc.subjectCage compoundsen
dc.subjectIridiumen
dc.subjectPalladiumen
dc.subjectPhotochemistryen
dc.subjectSelf-assemblyen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectBDCen
dc.subject.lccQDen
dc.titleHomochiral emissive Λ8- andΔ8-[Ir8Pd4]16+ supramolecular cagesen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. Organic Semiconductor Centreen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1002/chem.201703273
dc.description.statusPeer revieweden
dc.date.embargoedUntil2017-09-12
dc.identifier.grantnumberEP/M02105X/1en


This item appears in the following Collection(s)

Show simple item record

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.