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Ionothermal synthesis and characterization of CoAPO-34 molecular sieve
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dc.contributor.author | Musa, Mazlina | |
dc.contributor.author | Dawson, Daniel M. | |
dc.contributor.author | Ashbrook, Sharon E. | |
dc.contributor.author | Morris, Russell E. | |
dc.date.accessioned | 2017-09-28T23:32:12Z | |
dc.date.available | 2017-09-28T23:32:12Z | |
dc.date.issued | 2017-02 | |
dc.identifier | 246364872 | |
dc.identifier | 3ab0966c-9b5b-4caa-9663-981bfeb441f9 | |
dc.identifier | 84992493228 | |
dc.identifier | 000389284300038 | |
dc.identifier.citation | Musa , M , Dawson , D M , Ashbrook , S E & Morris , R E 2017 , ' Ionothermal synthesis and characterization of CoAPO-34 molecular sieve ' , Microporous and Mesoporous Materials , vol. 239 , pp. 336-341 . https://doi.org/10.1016/j.micromeso.2016.09.045 | en |
dc.identifier.issn | 1387-1811 | |
dc.identifier.other | RIS: urn:58C6B606A3FA5F21F19B7A59A5C3FB37 | |
dc.identifier.uri | https://hdl.handle.net/10023/11756 | |
dc.description.abstract | The cobalt-doped aluminophosphate molecular sieve, CoAPO-34 (with the chabazite-type topology) was prepared under ionothermal conditions using 1-ethyl-3-methylimidazolium bromide (EMIMBr) ionic liquid in presence of 1,6-hexanediamine (HDA). The HDA is not incorporated in CoAPO-34, but is required to mediate the availability of Co2+ during the synthesis. The material was characterized using powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and solid-state NMR spectroscopy. Wideline 31P NMR spectroscopy showed broad signals (∼5000–10000 ppm wide), confirming that paramagnetic cobalt ions are successfully incorporated within the framework of the materials. | |
dc.format.extent | 6 | |
dc.format.extent | 966861 | |
dc.language.iso | eng | |
dc.relation.ispartof | Microporous and Mesoporous Materials | en |
dc.subject | CoAPO-34 | en |
dc.subject | Aluminophosphate | en |
dc.subject | Ionothermal synthesis | en |
dc.subject | 1-ethyl-3-methylimidazolium bromide | en |
dc.subject | 1,6-hexanediamine | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Ionothermal synthesis and characterization of CoAPO-34 molecular sieve | en |
dc.type | Journal item | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1016/j.micromeso.2016.09.045 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2017-09-28 |
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