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Exploring the self-assembly and energy transfer of dynamic supramolecular iridium-porphyrin systems
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dc.contributor.author | Rota Martir, Diego | |
dc.contributor.author | Hedley, Gordon J. | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Escudero, Daniel | |
dc.contributor.author | Jacquemin, Denis | |
dc.contributor.author | Kosikova, Tamara | |
dc.contributor.author | Philp, Douglas | |
dc.contributor.author | Dawson, Daniel M. | |
dc.contributor.author | Ashbrook, Sharon E. | |
dc.contributor.author | Samuel, Ifor D. W. | |
dc.contributor.author | Zysman-Colman, Eli | |
dc.date.accessioned | 2017-09-22T23:32:24Z | |
dc.date.available | 2017-09-22T23:32:24Z | |
dc.date.issued | 2016-11-22 | |
dc.identifier | 246059548 | |
dc.identifier | 089ce43a-e67e-4d9a-9d7d-927a3d397ba8 | |
dc.identifier | 84994627209 | |
dc.identifier | 000387621400019 | |
dc.identifier.citation | Rota Martir , D , Hedley , G J , Cordes , D B , Slawin , A M Z , Escudero , D , Jacquemin , D , Kosikova , T , Philp , D , Dawson , D M , Ashbrook , S E , Samuel , I D W & Zysman-Colman , E 2016 , ' Exploring the self-assembly and energy transfer of dynamic supramolecular iridium-porphyrin systems ' , Dalton Transactions , vol. 45 , no. 43 , pp. 17195-17205 . https://doi.org/10.1039/C6DT02619B | en |
dc.identifier.issn | 1477-9226 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/28023963 | |
dc.identifier.other | ORCID: /0000-0002-4538-6782/work/56638975 | |
dc.identifier.other | ORCID: /0000-0001-7183-6022/work/56639109 | |
dc.identifier.other | ORCID: /0000-0002-9198-4302/work/56639243 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861827 | |
dc.identifier.other | ORCID: /0000-0002-8110-4535/work/34029110 | |
dc.identifier.uri | https://hdl.handle.net/10023/11723 | |
dc.description | EZ-C acknowledges the University of St Andrews for financial support. IDWS acknowledges support from EPSRC (EP/J009016) and the European Research Council (grant 321305). IDWS also acknowledges support from a Royal Society Wolfson research merit award. DJ acknowledges the European Research Council (grant: 278845) and the RFI Lumomat for financial support. | en |
dc.description.abstract | We present the first examples of dynamic supramolecular systems composed of cyclometalated Ir(III) complexes of the form of [Ir(C^N)2(N^N)]PF6 (where C^N is mesppy = 2-phenyl-4-mesitylpyridinato and dFmesppy = 2-(4,6-difluorophenyl)-4-mesitylpyridinato and N^N is 4,4':2',2'':4'',4'''-quaterpyridine, qpy) and zinc tetraphenylporphyrin (ZnTPP), assembled through non-covalent interactions between the distal pyridine moieties of the qpy ligand located on the iridium complex and the zinc of the ZnTPP. The assemblies have been comprehensively characterized by a series of analytical techniques (1H NMR titration experiments, 2D COSY and HETCOR NMR spectra and low temperature 1H NMR spectroscopy) and the crystal structures have been elucidated by X-ray diffraction. The optoelectronic properties of the assemblies and the electronic interaction between the iridium and porphyrin chromophoric units have been explored with detailed photophysical measurements, supported by time-dependent density functional theory (TD-DFT) calculations. | |
dc.format.extent | 10 | |
dc.format.extent | 2215319 | |
dc.language.iso | eng | |
dc.relation.ispartof | Dalton Transactions | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Exploring the self-assembly and energy transfer of dynamic supramolecular iridium-porphyrin systems | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | European Research Council | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Organic Semiconductor Centre | en |
dc.contributor.institution | University of St Andrews. School of Physics and Astronomy | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Biomedical Sciences Research Complex | en |
dc.contributor.institution | University of St Andrews. Condensed Matter Physics | en |
dc.identifier.doi | 10.1039/C6DT02619B | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2017-09-22 | |
dc.identifier.url | http://www.rsc.org/suppdata/c6/dt/c6dt02619b/c6dt02619b1.pdf | en |
dc.identifier.grantnumber | N/A | en |
dc.identifier.grantnumber | en |
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