Files in this item
Exploring the self-assembly and energy transfer of dynamic supramolecular iridium-porphyrin systems
Item metadata
dc.contributor.author | Rota Martir, Diego | |
dc.contributor.author | Hedley, Gordon J. | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Escudero, Daniel | |
dc.contributor.author | Jacquemin, Denis | |
dc.contributor.author | Kosikova, Tamara | |
dc.contributor.author | Philp, Douglas | |
dc.contributor.author | Dawson, Daniel M. | |
dc.contributor.author | Ashbrook, Sharon E. | |
dc.contributor.author | Samuel, Ifor D. W. | |
dc.contributor.author | Zysman-Colman, Eli | |
dc.date.accessioned | 2017-09-22T23:32:24Z | |
dc.date.available | 2017-09-22T23:32:24Z | |
dc.date.issued | 2016-11-22 | |
dc.identifier.citation | Rota Martir , D , Hedley , G J , Cordes , D B , Slawin , A M Z , Escudero , D , Jacquemin , D , Kosikova , T , Philp , D , Dawson , D M , Ashbrook , S E , Samuel , I D W & Zysman-Colman , E 2016 , ' Exploring the self-assembly and energy transfer of dynamic supramolecular iridium-porphyrin systems ' , Dalton Transactions , vol. 45 , no. 43 , pp. 17195-17205 . https://doi.org/10.1039/C6DT02619B | en |
dc.identifier.issn | 1477-9226 | |
dc.identifier.other | PURE: 246059548 | |
dc.identifier.other | PURE UUID: 089ce43a-e67e-4d9a-9d7d-927a3d397ba8 | |
dc.identifier.other | Scopus: 84994627209 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/28023963 | |
dc.identifier.other | ORCID: /0000-0002-4538-6782/work/56638975 | |
dc.identifier.other | ORCID: /0000-0001-7183-6022/work/56639109 | |
dc.identifier.other | ORCID: /0000-0002-9198-4302/work/56639243 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861827 | |
dc.identifier.other | ORCID: /0000-0002-8110-4535/work/34029110 | |
dc.identifier.other | WOS: 000387621400019 | |
dc.identifier.uri | https://hdl.handle.net/10023/11723 | |
dc.description | EZ-C acknowledges the University of St Andrews for financial support. IDWS acknowledges support from EPSRC (EP/J009016) and the European Research Council (grant 321305). IDWS also acknowledges support from a Royal Society Wolfson research merit award. DJ acknowledges the European Research Council (grant: 278845) and the RFI Lumomat for financial support. | en |
dc.description.abstract | We present the first examples of dynamic supramolecular systems composed of cyclometalated Ir(III) complexes of the form of [Ir(C^N)2(N^N)]PF6 (where C^N is mesppy = 2-phenyl-4-mesitylpyridinato and dFmesppy = 2-(4,6-difluorophenyl)-4-mesitylpyridinato and N^N is 4,4':2',2'':4'',4'''-quaterpyridine, qpy) and zinc tetraphenylporphyrin (ZnTPP), assembled through non-covalent interactions between the distal pyridine moieties of the qpy ligand located on the iridium complex and the zinc of the ZnTPP. The assemblies have been comprehensively characterized by a series of analytical techniques (1H NMR titration experiments, 2D COSY and HETCOR NMR spectra and low temperature 1H NMR spectroscopy) and the crystal structures have been elucidated by X-ray diffraction. The optoelectronic properties of the assemblies and the electronic interaction between the iridium and porphyrin chromophoric units have been explored with detailed photophysical measurements, supported by time-dependent density functional theory (TD-DFT) calculations. | |
dc.format.extent | 10 | |
dc.language.iso | eng | |
dc.relation.ispartof | Dalton Transactions | en |
dc.rights | Copyright 2016 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C6DT02619B | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Exploring the self-assembly and energy transfer of dynamic supramolecular iridium-porphyrin systems | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | European Research Council | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Organic Semiconductor Centre | en |
dc.contributor.institution | University of St Andrews. School of Physics and Astronomy | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Biomedical Sciences Research Complex | en |
dc.contributor.institution | University of St Andrews. Condensed Matter Physics | en |
dc.identifier.doi | https://doi.org/10.1039/C6DT02619B | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2017-09-22 | |
dc.identifier.url | http://www.rsc.org/suppdata/c6/dt/c6dt02619b/c6dt02619b1.pdf | en |
dc.identifier.grantnumber | N/A | en |
dc.identifier.grantnumber | en |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.