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dc.contributor.authorPrice, Robert
dc.contributor.authorCassidy, Mark
dc.contributor.authorSchuler, J. Andreas
dc.contributor.authorMai, Andreas
dc.contributor.authorIrvine, John T. S.
dc.date.accessioned2017-09-11T15:30:13Z
dc.date.available2017-09-11T15:30:13Z
dc.date.issued2017-07-23
dc.identifier251032277
dc.identifier2be5e14a-263b-40a2-8f52-2b72eb258fe1
dc.identifier85028458567
dc.identifier000432566702030
dc.identifier.citationPrice , R , Cassidy , M , Schuler , J A , Mai , A & Irvine , J T S 2017 , Development and testing of impregnated La 0.20 Sr 0.25 Ca 0.45 TiO 3 anode microstructures for solid oxide fuel cells . in 15th International Symposium on Solid Oxide Fuel Cells (SOFC-XV) . ECS Transactions , no. 1 , vol. 78 , Electrochemical Society , pp. 1385-1395 , SOFC-XV: 15th International Symposium on Solid Oxide Fuel Cells July 23, 2017 - July 28, 2017 , Hollywood , Florida , United States , 23/07/17 . https://doi.org/10.1149/07801.1385ecsten
dc.identifier.citationconferenceen
dc.identifier.issn1938-6737
dc.identifier.othercrossref: 10.1149/07801.1385ecst
dc.identifier.otherORCID: /0000-0002-8394-3359/work/68280887
dc.identifier.urihttps://hdl.handle.net/10023/11643
dc.descriptionFunding: EPSRC project EP/M014304/1 “Tailoring of Microstructural Evolution in Impregnated SOFC Electrodes”, the University of St Andrews and HEXIS AG.en
dc.description.abstractThe A-site deficient perovskite: La0.20Sr0.25Ca0.45TiO3 (LSCTA-) is a mixed ionic and electronic conductor (MIEC) which shows promising performance as a Solid Oxide Fuel Cell (SOFC) anode ‘backbone’ material, when impregnated with metallic and oxide-ion conducting electrocatalysts. Here, we present data on the complete ceramic processing and optimisation of the LSCTA- ‘backbone’ microstructure, in order to improve current distribution throughout the anode. Through control of ink rheology, screen printing parameters and sintering protocol an advantageous LSCTA- microstructural architecture was developed, exhibiting an ‘effective’ conductivity of 21 S cm-1. Incorporation of this LSCTA- anode microstructure into SOFC and impregnation with Ce0.80Gd0.20O1.9 and either Ni, Ru, Rh, Pt or Pd resulted in promising initial performances during fuel cell testing in a fuel stream of 97% H2:3% H2O. Area Specific Resistances of 0.41 Ω cm2 and 0.39 Ω cm2 were achieved with anodes containing Rh/CGO and Pd/CGO, respectively.
dc.format.extent758910
dc.language.isoeng
dc.publisherElectrochemical Society
dc.relation.ispartof15th International Symposium on Solid Oxide Fuel Cells (SOFC-XV)en
dc.relation.ispartofseriesECS Transactionsen
dc.subjectQC Physicsen
dc.subjectQD Chemistryen
dc.subjectTK Electrical engineering. Electronics Nuclear engineeringen
dc.subjectNDASen
dc.subject.lccQCen
dc.subject.lccQDen
dc.subject.lccTKen
dc.titleDevelopment and testing of impregnated La0.20Sr0.25Ca0.45TiO3 anode microstructures for solid oxide fuel cellsen
dc.typeConference itemen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1149/07801.1385ecst
dc.identifier.grantnumberEP/M014304/1en


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