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Reconstructing coral calcification fluid dissolved inorganic carbon chemistry from skeletal boron : an exploration of potential controls on coral aragonite B/Ca
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dc.contributor.author | Allison, Nicola | |
dc.date.accessioned | 2017-09-04T13:30:09Z | |
dc.date.available | 2017-09-04T13:30:09Z | |
dc.date.issued | 2017-08 | |
dc.identifier.citation | Allison , N 2017 , ' Reconstructing coral calcification fluid dissolved inorganic carbon chemistry from skeletal boron : an exploration of potential controls on coral aragonite B/Ca ' , Heliyon , vol. 3 , no. 8 , e00387 . https://doi.org/10.1016/j.heliyon.2017.e00387 | en |
dc.identifier.issn | 2405-8440 | |
dc.identifier.other | PURE: 251006820 | |
dc.identifier.other | PURE UUID: 787f4bfd-c2f8-43d7-9631-b6159b9dbdc4 | |
dc.identifier.other | RIS: urn:3271984573E97ED52AC15CA4C8450AF2 | |
dc.identifier.other | Scopus: 85028315474 | |
dc.identifier.other | ORCID: /0000-0003-3720-1917/work/42594123 | |
dc.identifier.other | WOS: 000432024600004 | |
dc.identifier.uri | https://hdl.handle.net/10023/11610 | |
dc.description | This work was supported by the UK Natural Environment Research Council (award NE/I022973/1). | en |
dc.description.abstract | The boron geochemistry of coral skeletons reflects the dissolved inorganic carbon (DIC) chemistry of the calcification fluid from which the skeletons precipitates and may be a valuable tool to investigate the effects of climate change on coral calcification. In this paper I calculate the predicted B/Ca of aragonite precipitating from seawater based fluids as a function of pH, [DIC] and [Ca2+]. I consider how different co-precipitating DIC species affect aragonite B/Ca and also estimate the impact of variations in the B(OH)4−/co-precipitating DIC aragonite partition coefficient (KD), which may be associated with changes in the DIC and Ca2+ chemistry of the calcification fluid. The coral skeletal B/Ca versus calcification fluid pH relationships reported previously can be reproduced by estimating B(OH)4− and co-precipitating DIC speciation as a function of pHCF and assuming that KD are constant i.e. unaffected by calcification fluid saturation state. Assuming that B(OH)4− co-precipitates with CO32−, then observed patterns can be reproduced by a fluid with approximately constant [DIC] i.e. increasing pHCF concentrates CO32−, as a function of DIC speciation. Assuming that B(OH)4− co-precipitates with HCO3− only or CO32− + HCO3− then the observed patterns can be reproduced if [DIC]CF and pHCF are positively related i.e. if DIC is increasingly concentrated in the calcification fluid at higher pHCF probably by CO2 diffusion into the calcification site. | |
dc.format.extent | 22 | |
dc.language.iso | eng | |
dc.relation.ispartof | Heliyon | en |
dc.rights | © 2017 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). | en |
dc.subject | Geochemistry | en |
dc.subject | Geology | en |
dc.subject | Oceanography | en |
dc.subject | QE Geology | en |
dc.subject | QD Chemistry | en |
dc.subject | GC Oceanography | en |
dc.subject | NDAS | en |
dc.subject | SDG 13 - Climate Action | en |
dc.subject.lcc | QE | en |
dc.subject.lcc | QD | en |
dc.subject.lcc | GC | en |
dc.title | Reconstructing coral calcification fluid dissolved inorganic carbon chemistry from skeletal boron : an exploration of potential controls on coral aragonite B/Ca | en |
dc.type | Journal article | en |
dc.contributor.sponsor | NERC | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. School of Earth & Environmental Sciences | en |
dc.contributor.institution | University of St Andrews. Marine Alliance for Science & Technology Scotland | en |
dc.contributor.institution | University of St Andrews. Scottish Oceans Institute | en |
dc.contributor.institution | University of St Andrews. St Andrews Isotope Geochemistry | en |
dc.identifier.doi | https://doi.org/10.1016/j.heliyon.2017.e00387 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.sciencedirect.com/science/article/pii/S2405844017318637#appd001 | en |
dc.identifier.grantnumber | NE/I022973/1 | en |
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