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dc.contributor.authorSanhoury, M. Abderrahmane
dc.contributor.authorMbarek, T.
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorDhia, M. T. Ben
dc.contributor.authorKhaddar, M. R.
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2017-08-31T23:32:08Z
dc.date.available2017-08-31T23:32:08Z
dc.date.issued2016-11-24
dc.identifier.citationSanhoury , M A , Mbarek , T , Slawin , A M Z , Dhia , M T B , Khaddar , M R & Woollins , J D 2016 , ' Synthesis, characterization and structures of cadmium(II) and mercury(II) complexes with bis(dipiperidinylphosphino)methylamine dichalcogenides ' , Polyhedron , vol. 119 , pp. 106-111 . https://doi.org/10.1016/j.poly.2016.08.031en
dc.identifier.issn0277-5387
dc.identifier.otherPURE: 244781904
dc.identifier.otherPURE UUID: dd84a704-b60f-4f2b-b0df-c6e95fd2f0cc
dc.identifier.otherScopus: 84986879925
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861647
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779153
dc.identifier.otherWOS: 000389165400012
dc.identifier.urihttp://hdl.handle.net/10023/11580
dc.descriptionThe authors are grateful to the Tunisian Ministry of High Education and Scientific Research for financial support (LR99ES14) of this research.en
dc.description.abstractTwo new bidentate phosphine dichalcogenide ligands of the type MeN(Pip2PE)2 [(Pip = piperidinyl; E = S ( 1 ) or Se ( 2 )] and their cadmium(II) and mercury(II) chloride complexes MCl2{MeN(Pip2PE)2} [M = Cd; E = S ( 3 ); Se ( 4 ) or M = Hg; L = S ( 5 ); Se ( 6 )] were prepared and characterized by elemental analysis, IR, multinuclear (31P, 77Se and 113Cd) NMR spectroscopy and single crystal X-ray analyses. Ligands 1 and 2 were found to adopt anti conformation structures in the solid state in which both P=E groups are trans to each other. Complexes 3 - 6 are comprised of one ligand coordinated in a bidentate fashion to the metal centre in a distorted tetrahedral arrangement [98.46(3)-121.24(4)°]. The P=S bond lengths of 1.999(15)-2.003(14) Å in the complex ( 3 ) are slightly elongated compared to those in free ligand [1.933(15)-1.950(14) Å]. The results are discussed and compared with closely related analogues.
dc.format.extent6
dc.language.isoeng
dc.relation.ispartofPolyhedronen
dc.rights© 2016 Elsevier Ltd. All rights reserved. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1016/j.poly.2016.08.031en
dc.subjectCadmiumen
dc.subjectMercury complexen
dc.subjectbis(dichlorophosphino)methylamineen
dc.subject31Pen
dc.subject77Seen
dc.subject113Cden
dc.subjectNMRen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleSynthesis, characterization and structures of cadmium(II) and mercury(II) complexes with bis(dipiperidinylphosphino)methylamine dichalcogenidesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews.Office of the Principalen
dc.identifier.doihttps://doi.org/10.1016/j.poly.2016.08.031
dc.description.statusPeer revieweden
dc.date.embargoedUntil2017-08-31


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