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dc.contributor.authorGiagloglou, Kyriakos
dc.contributor.authorPayne, Julia L.
dc.contributor.authorCrouch, Christina
dc.contributor.authorGover, Richard
dc.contributor.authorConnor, Paul A.
dc.contributor.authorIrvine, John T. S.
dc.identifier.citationGiagloglou , K , Payne , J L , Crouch , C , Gover , R , Connor , P A & Irvine , J T S 2017 , ' Synthesis and electrochemical study of CoNi 2 S 4 as a novel cathode material in a primary Li thermal battery ' , Journal of The Electrochemical Society , vol. 164 , no. 9 , pp. A2159-A2163 .
dc.identifier.otherPURE: 250651810
dc.identifier.otherPURE UUID: 9e7cf426-4be7-4465-89b9-4fd8f947ab47
dc.identifier.otherScopus: 85042381549
dc.identifier.otherORCID: /0000-0002-1492-7590/work/60427201
dc.identifier.otherWOS: 000413256400041
dc.identifier.otherORCID: /0000-0003-3324-6018/work/60888223
dc.identifier.otherORCID: /0000-0002-8394-3359/work/68280759
dc.descriptionThe authors acknowledge support and contribution from AWE Plc for this work, and thank the STFC for neutron diffraction beam-time.en
dc.description.abstractIn this work CoNi2S4 was investigated as a candidate cathode material for Li thermal batteries. The CoNi2S4 was synthesized by a solid state reaction at 550◦C in a sealed quartz tube. Neutron powder diffraction was utilized to confirm normal spinel structure up to 200◦C, however, there was cation disorder above this temperature. The electrochemical properties of the batteries were investigated at 500◦C by galvanostatic discharge to elucidate the mechanism and the products NiS, Co3S4 and Co9S8 of the discharge mechanism were confirmed using powder X-ray diffraction. CoNi2S4 exhibits two voltage plateaus vs Li13Si4 at 500◦C, one at 1.75 V and the second at 1.50 V. CoNi2S4 has an overall capacity of 318 mA h g−1 from OCV 2.58 V to 1.25 V vs Li13Si4 which is comparable to that of the well-known metal disulfides
dc.relation.ispartofJournal of The Electrochemical Societyen
dc.rights© The Author(s) 2017. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY,, which permits unrestricted reuse of the work in any medium, provided the original work is properly cited.en
dc.subjectDischarge at high temperatureen
dc.subjectLi thermal batteryen
dc.subjectSolid state reactionen
dc.subjectQD Chemistryen
dc.titleSynthesis and electrochemical study of CoNi2S4 as a novel cathode material in a primary Li thermal batteryen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.St Andrews Sustainability Instituteen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.description.statusPeer revieweden

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