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Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC = N-Heterocyclic carbene, X, Y = Cl, Br) species
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dc.contributor.author | Santoro, Orlando | |
dc.contributor.author | Nahra, Fady | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Nolan, Steven P. | |
dc.contributor.author | Cazin, Catherine S. J. | |
dc.date.accessioned | 2017-08-15T08:44:07Z | |
dc.date.available | 2017-08-15T08:44:07Z | |
dc.date.issued | 2016-11 | |
dc.identifier.citation | Santoro , O , Nahra , F , Cordes , D B , Slawin , A M Z , Nolan , S P & Cazin , C S J 2016 , ' Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY 2 ] (NHC = N -Heterocyclic carbene, X, Y = Cl, Br) species ' , Journal of Molecular Catalysis A: Chemical , vol. 423 , pp. 85-91 . https://doi.org/10.1016/j.molcata.2016.05.031 | en |
dc.identifier.issn | 1381-1169 | |
dc.identifier.other | PURE: 243242924 | |
dc.identifier.other | PURE UUID: f15e7594-616f-4a1a-b9c1-feeff7bbec27 | |
dc.identifier.other | RIS: urn:F211584CF5ED5C5518D1734160FAC7F3 | |
dc.identifier.other | Scopus: 84975789739 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/28023966 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861646 | |
dc.identifier.other | WOS: 000383827600010 | |
dc.identifier.uri | https://hdl.handle.net/10023/11453 | |
dc.description | The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C) and the EPSRC (EP/J500549/1, EP/K00445X/1) for funding. S.P. N. acknowledges support from KSU. | en |
dc.description.abstract | The synthesis and characterization of imidazol(in)ium-based zinc(II) halide salts are reported. These compounds present interesting structural features and exhibit high stability. Their catalytic activity was explored in the methylation of amines with CO2 and PhSiH3. | |
dc.format.extent | 7 | |
dc.language.iso | eng | |
dc.relation.ispartof | Journal of Molecular Catalysis A: Chemical | en |
dc.rights | © 2016 Published by Elsevier B.V. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1016/j.molcata.2016.05.031 | en |
dc.subject | N-Heterocyclic carbenes | en |
dc.subject | Zinc | en |
dc.subject | methylation | en |
dc.subject | CO2 | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC = N-Heterocyclic carbene, X, Y = Cl, Br) species | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | The Royal Society | en |
dc.contributor.sponsor | EPSRC | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1016/j.molcata.2016.05.031 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2017-06-04 | |
dc.identifier.grantnumber | EP/K00445X/1 | en |
dc.identifier.grantnumber | UF100691 | en |
dc.identifier.grantnumber | EP/J018139/1 | en |
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