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Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC = N-Heterocyclic carbene, X, Y = Cl, Br) species

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dc.contributor.authorSantoro, Orlando
dc.contributor.authorNahra, Fady
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorNolan, Steven P.
dc.contributor.authorCazin, Catherine S. J.
dc.date.accessioned2017-08-15T08:44:07Z
dc.date.available2017-08-15T08:44:07Z
dc.date.issued2016-11
dc.identifier243242924
dc.identifierf15e7594-616f-4a1a-b9c1-feeff7bbec27
dc.identifier84975789739
dc.identifier000383827600010
dc.identifier.citationSantoro , O , Nahra , F , Cordes , D B , Slawin , A M Z , Nolan , S P & Cazin , C S J 2016 , ' Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY 2 ] (NHC = N -Heterocyclic carbene, X, Y = Cl, Br) species ' , Journal of Molecular Catalysis A: Chemical , vol. 423 , pp. 85-91 . https://doi.org/10.1016/j.molcata.2016.05.031en
dc.identifier.issn1381-1169
dc.identifier.otherRIS: urn:F211584CF5ED5C5518D1734160FAC7F3
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28023966
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861646
dc.identifier.urihttps://hdl.handle.net/10023/11453
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C) and the EPSRC (EP/J500549/1, EP/K00445X/1) for funding. S.P. N. acknowledges support from KSU.en
dc.description.abstractThe synthesis and characterization of imidazol(in)ium-based zinc(II) halide salts are reported. These compounds present interesting structural features and exhibit high stability. Their catalytic activity was explored in the methylation of amines with CO2 and PhSiH3.
dc.format.extent7
dc.format.extent1316840
dc.language.isoeng
dc.relation.ispartofJournal of Molecular Catalysis A: Chemicalen
dc.subjectN-Heterocyclic carbenesen
dc.subjectZincen
dc.subjectmethylationen
dc.subjectCO2en
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleSynthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC = N-Heterocyclic carbene, X, Y = Cl, Br) speciesen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorThe Royal Societyen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1016/j.molcata.2016.05.031
dc.description.statusPeer revieweden
dc.date.embargoedUntil2017-06-04
dc.identifier.grantnumberEP/K00445X/1en
dc.identifier.grantnumberUF100691en
dc.identifier.grantnumberEP/J018139/1en


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