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Impact of the metal centre and functionalization on the mechanical behaviour of MIL-53 metal–organic frameworks

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Date
27/09/2016
Author
Yot, Pascal G.
Yang, Ke
Guillerm, Vincent
Ragon, Florence
Dmitriev, Vladimir
Parisiades, Paraskevas
Elkaïm, Erik
Devic, Thomas
Horcajada, Patricia
Serre, Christian
Stock, Norbert
Mowat, John P. S.
Wright, Paul A.
Férey, Gérard
Maurin, Guillaume
Keywords
Metal–organic frameworks
Mechanical properties
X-ray diffraction
Phase transitions
Substituent effects
QD Chemistry
NDAS
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Abstract
An extended series of MIL-53(M)_X metal–organic frameworks (MIL = Materials of Institute Lavoisier; M = Al, Cr, Fe, Sc; X = Cl, CH3, NO2) have been systematically investiaged to explore the impact of the nature of both the metal centre and the functions grafted on to the organic linker on the mechanical behaviour of this family of highly flexible hybrid porous frameworks under the application of an external pressure of up to 3 GPa. The high-pressure X-ray diffraction measurements allowed the characterization of the pressure-induced phase transitions of the hydrated structures, the associated volume changes/pressure transitions, and their mechanical resilience through the determination of their bulk moduli.
Citation
Yot , P G , Yang , K , Guillerm , V , Ragon , F , Dmitriev , V , Parisiades , P , Elkaïm , E , Devic , T , Horcajada , P , Serre , C , Stock , N , Mowat , J P S , Wright , P A , Férey , G & Maurin , G 2016 , ' Impact of the metal centre and functionalization on the mechanical behaviour of MIL-53 metal–organic frameworks ' , European Journal of Inorganic Chemistry , vol. 2016 , no. 27 , pp. 4424–4429 . https://doi.org/10.1002/ejic.201600263
Publication
European Journal of Inorganic Chemistry
Status
Peer reviewed
DOI
https://doi.org/10.1002/ejic.201600263
ISSN
1099-0682
Type
Journal article
Rights
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1002/ejic.201600263
 
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1002/ejic.201600263
Description
The French National Agency for Research ANR “MODS” (ANR-12-BS10-0005) is thanked for its financial support.
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  • University of St Andrews Research
URL
http://onlinelibrary.wiley.com/doi/10.1002/ejic.201600263/abstract#footer-support-info
URI
http://hdl.handle.net/10023/11147

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