Impact of the metal centre and functionalization on the mechanical behaviour of MIL-53 metal–organic frameworks
Abstract
An extended series of MIL-53(M)_X metal–organic frameworks (MIL = Materials of Institute Lavoisier; M = Al, Cr, Fe, Sc; X = Cl, CH3, NO2) have been systematically investiaged to explore the impact of the nature of both the metal centre and the functions grafted on to the organic linker on the mechanical behaviour of this family of highly flexible hybrid porous frameworks under the application of an external pressure of up to 3 GPa. The high-pressure X-ray diffraction measurements allowed the characterization of the pressure-induced phase transitions of the hydrated structures, the associated volume changes/pressure transitions, and their mechanical resilience through the determination of their bulk moduli.
Citation
Yot , P G , Yang , K , Guillerm , V , Ragon , F , Dmitriev , V , Parisiades , P , Elkaïm , E , Devic , T , Horcajada , P , Serre , C , Stock , N , Mowat , J P S , Wright , P A , Férey , G & Maurin , G 2016 , ' Impact of the metal centre and functionalization on the mechanical behaviour of MIL-53 metal–organic frameworks ' , European Journal of Inorganic Chemistry , vol. 2016 , no. 27 , pp. 4424–4429 . https://doi.org/10.1002/ejic.201600263
Publication
European Journal of Inorganic Chemistry
Status
Peer reviewed
ISSN
1099-0682Type
Journal article
Rights
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1002/ejic.201600263 © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1002/ejic.201600263
Description
The French National Agency for Research ANR “MODS” (ANR-12-BS10-0005) is thanked for its financial support.Collections
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.