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dc.contributor.authorBidal, Yannick D.
dc.contributor.authorSantoro, Orlando
dc.contributor.authorMelaimi, Mohand
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorBertrand, Guy
dc.contributor.authorCazin, Catherine S. J.
dc.date.accessioned2017-05-30T23:33:37Z
dc.date.available2017-05-30T23:33:37Z
dc.date.issued2016-06-27
dc.identifier.citationBidal , Y D , Santoro , O , Melaimi , M , Cordes , D B , Slawin , A M Z , Bertrand , G & Cazin , C S J 2016 , ' Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N -heterocyclic carbenes ' Chemistry - A European Journal , vol. 22 , no. 27 , pp. 9404-9409 . https://doi.org/10.1002/chem.201601254en
dc.identifier.issn1521-3765
dc.identifier.otherPURE: 243306894
dc.identifier.otherPURE UUID: 522ad7d2-57c0-473b-b4b7-71a90959cd4b
dc.identifier.otherBibtex: urn:4a10a1ea389c1886afb3d12e87f8a95f
dc.identifier.otherScopus: 84971401706
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28023977
dc.identifier.urihttp://hdl.handle.net/10023/10880
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), the EPSRC (EP/J500549/1) and the DOE (DE-FG02-13ER16370) for financial support.en
dc.description.abstractCarbene transition-metal complexes have become a prevalent family of catalysts enabling numerous organic transformations. Their facile synthetic access is a matter of great importance. To this end, the CuI-NHC transfer methodology has emerged as a powerful alternative presenting attractive advantages over other methods. Herein, we report the remarkable ability of copper to transfer not only NHCs but also other types of carbenes such as abnormal NHCs (aNHCs), cyclic (alkyl)(amino)carbenes (CAACs), and mesoionic carbenes (MICs) to various transition metal precursors.en
dc.format.extent6en
dc.language.isoeng
dc.relation.ispartofChemistry - A European Journalen
dc.rights© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1002/chem.201601254en
dc.subjectAbnormalen
dc.subjectCAACen
dc.subjectCarbene transferen
dc.subjectCopperen
dc.subjectN-heterocyclic carbeneen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleGeneralization of the copper to late-transition-metal transmetallation to carbenes beyond N-heterocyclic carbenesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1002/chem.201601254
dc.description.statusPeer revieweden
dc.date.embargoedUntil30-05-20


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