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Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N-heterocyclic carbenes
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dc.contributor.author | Bidal, Yannick D. | |
dc.contributor.author | Santoro, Orlando | |
dc.contributor.author | Melaimi, Mohand | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Bertrand, Guy | |
dc.contributor.author | Cazin, Catherine S. J. | |
dc.date.accessioned | 2017-05-30T23:33:37Z | |
dc.date.available | 2017-05-30T23:33:37Z | |
dc.date.issued | 2016-06-23 | |
dc.identifier | 243306894 | |
dc.identifier | 522ad7d2-57c0-473b-b4b7-71a90959cd4b | |
dc.identifier | 84971401706 | |
dc.identifier | 000380271100050 | |
dc.identifier.citation | Bidal , Y D , Santoro , O , Melaimi , M , Cordes , D B , Slawin , A M Z , Bertrand , G & Cazin , C S J 2016 , ' Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N -heterocyclic carbenes ' , Chemistry - A European Journal , vol. 22 , no. 27 , pp. 9404-9409 . https://doi.org/10.1002/chem.201601254 | en |
dc.identifier.issn | 0947-6539 | |
dc.identifier.other | Bibtex: urn:4a10a1ea389c1886afb3d12e87f8a95f | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/28023977 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861732 | |
dc.identifier.uri | https://hdl.handle.net/10023/10880 | |
dc.description | The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), the EPSRC (EP/J500549/1) and the DOE (DE-FG02-13ER16370) for financial support. | en |
dc.description.abstract | Carbene transition-metal complexes have become a prevalent family of catalysts enabling numerous organic transformations. Their facile synthetic access is a matter of great importance. To this end, the CuI-NHC transfer methodology has emerged as a powerful alternative presenting attractive advantages over other methods. Herein, we report the remarkable ability of copper to transfer not only NHCs but also other types of carbenes such as abnormal NHCs (aNHCs), cyclic (alkyl)(amino)carbenes (CAACs), and mesoionic carbenes (MICs) to various transition metal precursors. | |
dc.format.extent | 6 | |
dc.format.extent | 634310 | |
dc.language.iso | eng | |
dc.relation.ispartof | Chemistry - A European Journal | en |
dc.subject | Abnormal | en |
dc.subject | CAAC | en |
dc.subject | Carbene transfer | en |
dc.subject | Copper | en |
dc.subject | N-heterocyclic carbene | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject | BDC | en |
dc.subject.lcc | QD | en |
dc.title | Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N-heterocyclic carbenes | en |
dc.type | Journal article | en |
dc.contributor.sponsor | The Royal Society | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1002/chem.201601254 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2017-05-30 | |
dc.identifier.grantnumber | UF100691 | en |
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