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dc.contributor.authorBhattarai, Mohan K.
dc.contributor.authorPavunny, Shojan P.
dc.contributor.authorInstan, Alvaro A.
dc.contributor.authorScott, James Floyd
dc.contributor.authorKatiyar, Ram S.
dc.date.accessioned2017-05-19T10:30:09Z
dc.date.available2017-05-19T10:30:09Z
dc.date.issued2017-05-21
dc.identifier.citationBhattarai , M K , Pavunny , S P , Instan , A A , Scott , J F & Katiyar , R S 2017 , ' Effect of off-center ion substitution in morphotropic lead zirconate titanate ' , Journal of Applied Physics , vol. 121 , no. 19 , 194102 . https://doi.org/10.1063/1.4983526en
dc.identifier.issn0021-8979
dc.identifier.otherPURE: 249921104
dc.identifier.otherPURE UUID: f51467a8-99d5-4941-a35f-4da75b624e72
dc.identifier.otherScopus: 85019630713
dc.identifier.otherWOS: 000401771800009
dc.identifier.urihttp://hdl.handle.net/10023/10799
dc.descriptionThis research was supported by the DOD Grant No. FA9550–16-1–0295. S.P.P. gratefully acknowledges the financial assistance from IFN-NSF under the Grant No. EPS-1002410.en
dc.description.abstractA detailed study of the effect of off-center donor ion (Sc3+) substitution on structural, microstructural, optical, dielectric, electrical and ferroelectric properties of morphotropic lead zirconate titanate electroceramics with the stoichiometric formula Pb0.85Sc0.10Zr0.53Ti0.47O3 (PSZT), synthesized using a high-energy solid-state reaction technique, was carried out. Powder x-ray diffractometry was used to identify the stabilized tetragonal phase (space group P4mm) with considerably reduced tetragonal strain, c/a = 1.005. An analysis of the thermal dependence of the Raman results indicated a smooth order-disorder displacive (ferroelectric-paraelectric) phase transition as revealed by the observed disappearance of the soft modes A1 (1TO) and A1 (2TO) above 460 K. The dielectric response of Pt/PSZT/Pt metal-ferroelectric-metal (MFM) capacitors was probed over a wide range of thermal excursions (85-600 K) and ac signal frequencies (102-106 Hz). Thermally activated dynamic and static conduction processes indicate hopping conduction mechanism (Eact ≤ 0.015 eV) and the formation of small polarons caused by the electron and/or hole-lattice (phonon) interaction (Eact ≥ 0.1 eV) at low (100−300 K) and high temperatures (300−600 K), respectively. The reduction in remnant polarization obtained is in good agreement with the largely reduced tetragonal strain observed in this sample, ( Pr ∝√(c/a-1) ). DC current conduction is dominated by Poole-Frenkel mechanism that assumes a Coulombic attraction between de-trapped electrons and positively charged stationary defects in the polycrystalline matrix.
dc.language.isoeng
dc.relation.ispartofJournal of Applied Physicsen
dc.rights© 2017, the Author(s). This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at aip.scitation.org / https://doi.org/10.1063/1.4983526en
dc.subjectQC Physicsen
dc.subjectT Technologyen
dc.subjectNDASen
dc.subject.lccQCen
dc.subject.lccTen
dc.titleEffect of off-center ion substitution in morphotropic lead zirconate titanateen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.School of Physics and Astronomyen
dc.contributor.institutionUniversity of St Andrews.Condensed Matter Physicsen
dc.identifier.doihttps://doi.org/10.1063/1.4983526
dc.description.statusPeer revieweden


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