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Targeted synthesis of two super-complex zeolites with embedded isoreticular structures
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dc.contributor.author | Shin, Jiho | |
dc.contributor.author | Xu, Hongyi | |
dc.contributor.author | Seo, Seungwan | |
dc.contributor.author | Guo, Peng | |
dc.contributor.author | Min, Jung Gi | |
dc.contributor.author | Cho, Jung | |
dc.contributor.author | Wright, Paul Anthony | |
dc.contributor.author | Zou, Diaodong | |
dc.contributor.author | Hong, Suk Bong | |
dc.date.accessioned | 2017-03-17T00:33:04Z | |
dc.date.available | 2017-03-17T00:33:04Z | |
dc.date.issued | 2016-04-11 | |
dc.identifier.citation | Shin , J , Xu , H , Seo , S , Guo , P , Min , J G , Cho , J , Wright , P A , Zou , D & Hong , S B 2016 , ' Targeted synthesis of two super-complex zeolites with embedded isoreticular structures ' , Angewandte Chemie International Edition , vol. 55 , no. 16 , pp. 4928-4932 . https://doi.org/10.1002/anie.201510726 | en |
dc.identifier.issn | 1521-3773 | |
dc.identifier.other | PURE: 241562684 | |
dc.identifier.other | PURE UUID: c80b1384-b520-43c5-b304-1ef5c9c98644 | |
dc.identifier.other | Scopus: 84977932621 | |
dc.identifier.other | WOS: 000374496100008 | |
dc.identifier.other | ORCID: /0000-0002-4243-9957/work/62668295 | |
dc.identifier.uri | https://hdl.handle.net/10023/10485 | |
dc.description.abstract | A novel structural coding approach combining structure solution, prediction, and the targeted synthesis of new zeolites with expanding complexity and embedded isoreticular structures was recently proposed. Using this approach, the structures of two new zeolites in the RHO family, PST-20 and PST-25, were predicted and synthesized. Herein, by extending this approach, the next two higher generation members of this family, PST-26 and PST-28, have been predicted and synthesized. These two zeolites have much larger unit cell volumes (422 655 Å3 and 614 912 Å3, respectively) than those of the lower generations. Their crystallization was confirmed by a combination of both powder X-ray and electron diffraction techniques. Aluminate and water concentrations in the synthetic mixture were found to be the two most critical factors influencing the structural expansion of embedded isoreticular zeolites under the synthetic conditions studied herein. | |
dc.language.iso | eng | |
dc.relation.ispartof | Angewandte Chemie International Edition | en |
dc.rights | © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1002/anie.201510726 | en |
dc.rights | © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1002/anie.201510726 | en |
dc.subject | Embedded isoreticular structures | en |
dc.subject | RHO family | en |
dc.subject | Structure prediction | en |
dc.subject | Synthesis design | en |
dc.subject | Zeolites | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Targeted synthesis of two super-complex zeolites with embedded isoreticular structures | en |
dc.type | Journal article | en |
dc.description.version | Postprint | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1002/anie.201510726 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2017-03-16 | |
dc.identifier.url | http://onlinelibrary.wiley.com/wol1/doi/10.1002/anie.201510726/suppinfo | en |
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