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Dynamic covalent assembly and disassembly of nanoparticle aggregates

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dc.contributor.authorBorsley, Stefan
dc.contributor.authorKay, Euan R.
dc.date.accessioned2017-03-16T00:35:34Z
dc.date.available2017-03-16T00:35:34Z
dc.date.issued2016-07-25
dc.identifier241566192
dc.identifier31d3263c-38a5-497c-a8e5-1940c518609e
dc.identifier84978851249
dc.identifier000379431000034
dc.identifier.citationBorsley , S & Kay , E R 2016 , ' Dynamic covalent assembly and disassembly of nanoparticle aggregates ' , Chemical Communications , vol. 52 , no. 58 , pp. 9117-9120 . https://doi.org/10.1039/C6CC00135Aen
dc.identifier.issn1359-7345
dc.identifier.otherORCID: /0000-0001-8177-6393/work/56862275
dc.identifier.urihttps://hdl.handle.net/10023/10476
dc.descriptionThis work was supported by the EPSRC (EP/K016342/1 and EP/J500549/1), the University of St Andrews and by a Royal Society of Edinburgh/Scottish Government Fellowship (E.R.K.).en
dc.description.abstractThe quantitative assembly and disassembly of a new type of dynamic covalent nanoparticle (NP) building block is reported. In situ spectroscopic characterization reveals constitutionally adaptive NP-bound monolayers of boronate esters. Ditopic linker molecules are used to produce covalently connected AuNP assemblies, displaying open dendritic morphologies, and which, despite being linked by covalent bonds, can be fully disassembled on application of an appropriate chemical stimulus.
dc.format.extent4
dc.format.extent755326
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectBDCen
dc.subject.lccQDen
dc.titleDynamic covalent assembly and disassembly of nanoparticle aggregatesen
dc.typeJournal articleen
dc.contributor.sponsorThe Royal Society of Edinburghen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doihttps://doi.org/10.1039/C6CC00135A
dc.description.statusPeer revieweden
dc.date.embargoedUntil2017-03-15
dc.identifier.grantnumbern/aen
dc.identifier.grantnumberEP/K016342/1en


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