Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane
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The all-cis isomer of 1,2,3,4-tetrafluorocyclopentane is prepared and characterised by NMR and X-ray crystallography and the experimental structure compared with theory. The structure has a similarly high polarity to all-cis tetrafluorocyclohexanes despite the increased conformational flexibility of a cyclopentane.
Fang , Z , Al-Maharik , N , Slawin , A M Z , Buehl , M & O'Hagan , D 2016 , ' Polar alicyclic rings: synthesis and structure of all cis -1,2,3,4-tetrafluorocyclopentane ' Chemical Communications , vol 52 , no. 29 , pp. 5116-5119 . DOI: 10.1039/C6CC01348A
Copyright 2016 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C6CC01348A
The authors are grateful to the Chinese Scholarship Council for Studentship support (ZF), to EPSRC for financial support and to the EPSRC National Mass Spectrometry Service at Swansea for analytical support. DO’H thanks the Royal Society for a Wolfson Research Merit Award.
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